volume 354 issue 6 pages 1061-1068

Ligand-Free Buchwald-Hartwig Aromatic Aminations of Aryl Halides Catalyzed by Low-Leaching and Highly Recyclable Sulfur-Modified Gold-Supported Palladium Material

Publication typeJournal Article
Publication date2012-04-13
scimago Q1
wos Q1
SJR0.930
CiteScore8.0
Impact factor4.0
ISSN16154150, 16154169
General Chemistry
Abstract
A stable heterogeneous catalyst precursor, sulfur-modified gold-supported palladium material (SAPd), has proved to be an excellent source of leached, ligand-free, Pd for the amination of aryl bromides and chlorides. The reaction-enabling catalyst is provided in situ as leached Pd in low catalyst loading (0.21±0.02 mol%). This allows the precatalyst (SAPd) to be filtered off and used for a minimum of ten reaction cycles without loss of catalytic activity. SAPd released only trace amounts, less than 0.6 ppm, of highly active Pd during the reaction without any aggregation.
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GOST Copy
Al Amin M. et al. Ligand-Free Buchwald-Hartwig Aromatic Aminations of Aryl Halides Catalyzed by Low-Leaching and Highly Recyclable Sulfur-Modified Gold-Supported Palladium Material // Advanced Synthesis and Catalysis. 2012. Vol. 354. No. 6. pp. 1061-1068.
GOST all authors (up to 50) Copy
Al Amin M., Honma T., Hoshiya N., Shuto S., Arisawa M. Ligand-Free Buchwald-Hartwig Aromatic Aminations of Aryl Halides Catalyzed by Low-Leaching and Highly Recyclable Sulfur-Modified Gold-Supported Palladium Material // Advanced Synthesis and Catalysis. 2012. Vol. 354. No. 6. pp. 1061-1068.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/adsc.201100761
UR - https://doi.org/10.1002/adsc.201100761
TI - Ligand-Free Buchwald-Hartwig Aromatic Aminations of Aryl Halides Catalyzed by Low-Leaching and Highly Recyclable Sulfur-Modified Gold-Supported Palladium Material
T2 - Advanced Synthesis and Catalysis
AU - Al Amin, Mohammad
AU - Honma, Tetsuo
AU - Hoshiya, Naoyuki
AU - Shuto, Satoshi
AU - Arisawa, Mitsuhiro
PY - 2012
DA - 2012/04/13
PB - Wiley
SP - 1061-1068
IS - 6
VL - 354
SN - 1615-4150
SN - 1615-4169
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2012_Al Amin,
author = {Mohammad Al Amin and Tetsuo Honma and Naoyuki Hoshiya and Satoshi Shuto and Mitsuhiro Arisawa},
title = {Ligand-Free Buchwald-Hartwig Aromatic Aminations of Aryl Halides Catalyzed by Low-Leaching and Highly Recyclable Sulfur-Modified Gold-Supported Palladium Material},
journal = {Advanced Synthesis and Catalysis},
year = {2012},
volume = {354},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/adsc.201100761},
number = {6},
pages = {1061--1068},
doi = {10.1002/adsc.201100761}
}
MLA
Cite this
MLA Copy
Al Amin, Mohammad, et al. “Ligand-Free Buchwald-Hartwig Aromatic Aminations of Aryl Halides Catalyzed by Low-Leaching and Highly Recyclable Sulfur-Modified Gold-Supported Palladium Material.” Advanced Synthesis and Catalysis, vol. 354, no. 6, Apr. 2012, pp. 1061-1068. https://doi.org/10.1002/adsc.201100761.