Advanced Synthesis and Catalysis, volume 355, issue 4, pages 697-704
Aldehyde-Catalyzed Transition Metal-Free Dehydrative β-Alkylation of Methyl Carbinols with Alcohols
Publication type: Journal Article
Publication date: 2013-02-22
Journal:
Advanced Synthesis and Catalysis
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.4
ISSN: 16154150, 16154169
General Chemistry
Abstract
Different to the borrowing hydrogen strategy in which alcohols were activated by transition metal-catalyzed anaerobic dehydrogenation, the direct addition of aldehydes was found to be an effective but simpler way of alcohol activation that can lead to efficient and green aldehyde-catalyzed transition metal-free dehydrative C-alkylation of methyl carbinols with alcohols. Mechanistic studies revealed that the reaction proceeds via in situ formation of ketones by Oppenauer oxidation of the methyl carbinols by external aldehydes, aldol condensation, and Meerwein–Ponndorf–Verley (MPV)-type reduction of α,β-unsatutated ketones by substrate alcohols, affording the useful long chain alcohols and generating aldehydes and ketones as the by-products that will be recovered in the next condensation to finish the catalytic cycle.
Top-30
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1 publication, 1%
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1 publication, 1%
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Citations by publishers
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5
10
15
20
25
30
35
40
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Wiley
40 publications, 40%
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Royal Society of Chemistry (RSC)
25 publications, 25%
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American Chemical Society (ACS)
18 publications, 18%
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Elsevier
6 publications, 6%
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Springer Nature
4 publications, 4%
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Shanghai Institute of Organic Chemistry
3 publications, 3%
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 1%
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Thieme
1 publication, 1%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1%
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5
10
15
20
25
30
35
40
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Xu Q., Chen J., Liu Q. Aldehyde-Catalyzed Transition Metal-Free Dehydrative β-Alkylation of Methyl Carbinols with Alcohols // Advanced Synthesis and Catalysis. 2013. Vol. 355. No. 4. pp. 697-704.
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Xu Q., Chen J., Liu Q. Aldehyde-Catalyzed Transition Metal-Free Dehydrative β-Alkylation of Methyl Carbinols with Alcohols // Advanced Synthesis and Catalysis. 2013. Vol. 355. No. 4. pp. 697-704.
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TY - JOUR
DO - 10.1002/adsc.201200996
UR - https://doi.org/10.1002/adsc.201200996
TI - Aldehyde-Catalyzed Transition Metal-Free Dehydrative β-Alkylation of Methyl Carbinols with Alcohols
T2 - Advanced Synthesis and Catalysis
AU - Xu, Qing
AU - Chen, Jianhui
AU - Liu, Quan
PY - 2013
DA - 2013/02/22 00:00:00
PB - Wiley
SP - 697-704
IS - 4
VL - 355
SN - 1615-4150
SN - 1615-4169
ER -
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@article{2013_Xu,
author = {Qing Xu and Jianhui Chen and Quan Liu},
title = {Aldehyde-Catalyzed Transition Metal-Free Dehydrative β-Alkylation of Methyl Carbinols with Alcohols},
journal = {Advanced Synthesis and Catalysis},
year = {2013},
volume = {355},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/adsc.201200996},
number = {4},
pages = {697--704},
doi = {10.1002/adsc.201200996}
}
Cite this
MLA
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Xu, Qing, et al. “Aldehyde-Catalyzed Transition Metal-Free Dehydrative β-Alkylation of Methyl Carbinols with Alcohols.” Advanced Synthesis and Catalysis, vol. 355, no. 4, Feb. 2013, pp. 697-704. https://doi.org/10.1002/adsc.201200996.