Regio- and stereoselective dimerization of arylacetylenes and optical and electrochemical studies of (E)-1,3-enynes
Publication type: Journal Article
Publication date: 2014-07-17
scimago Q1
wos Q1
SJR: 0.930
CiteScore: 8.0
Impact factor: 4.0
ISSN: 16154150, 16154169
General Chemistry
Abstract
The N‐heterocyclic carbene palladium complex (SIPr)Pd(cinnamyl)Cl [SIPr=N,N′‐bis(2,4,6‐trimethylphenyl)‐4,5‐dihydroimidazol‐2‐ylidene) promotes regio‐ and stereospecific dimerization of a variety of arylalkynes to give (E)‐1,3‐enynes in good to excellent yields. An efficient and practical procedure for their synthesis was developed using a biphasic aqueous alkali/heptane system. Optical and electronic properties of (E)‐1,3‐enynes are highly tunable. Depending on the nature of the substituents, HOMO energies vary in the range 5.3–6.0 eV. (E)‐1,3‐Enynes can exhibit intense photoluminescence in the spectral region 350–500 nm.
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Total citations:
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Citations from 2024:
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Morozov O. S. et al. Regio- and stereoselective dimerization of arylacetylenes and optical and electrochemical studies of (E)-1,3-enynes // Advanced Synthesis and Catalysis. 2014. Vol. 356. No. 11-12. pp. 2671-2678.
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Morozov O. S., Asachenko A., Antonov D. V., Kochurov V. S., Paraschuk D. Y., Nechaev M. P. Regio- and stereoselective dimerization of arylacetylenes and optical and electrochemical studies of (E)-1,3-enynes // Advanced Synthesis and Catalysis. 2014. Vol. 356. No. 11-12. pp. 2671-2678.
Cite this
RIS
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TY - JOUR
DO - 10.1002/adsc.201400062
UR - https://onlinelibrary.wiley.com/doi/10.1002/adsc.201400062
TI - Regio- and stereoselective dimerization of arylacetylenes and optical and electrochemical studies of (E)-1,3-enynes
T2 - Advanced Synthesis and Catalysis
AU - Morozov, Oleg S
AU - Asachenko, Andrey
AU - Antonov, Denis V
AU - Kochurov, Vitaly S
AU - Paraschuk, Dmitry Yu.
AU - Nechaev, Mikhail Petrovich
PY - 2014
DA - 2014/07/17
PB - Wiley
SP - 2671-2678
IS - 11-12
VL - 356
SN - 1615-4150
SN - 1615-4169
ER -
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BibTex (up to 50 authors)
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@article{2014_Morozov,
author = {Oleg S Morozov and Andrey Asachenko and Denis V Antonov and Vitaly S Kochurov and Dmitry Yu. Paraschuk and Mikhail Petrovich Nechaev},
title = {Regio- and stereoselective dimerization of arylacetylenes and optical and electrochemical studies of (E)-1,3-enynes},
journal = {Advanced Synthesis and Catalysis},
year = {2014},
volume = {356},
publisher = {Wiley},
month = {jul},
url = {https://onlinelibrary.wiley.com/doi/10.1002/adsc.201400062},
number = {11-12},
pages = {2671--2678},
doi = {10.1002/adsc.201400062}
}
Cite this
MLA
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Morozov, Oleg S., et al. “Regio- and stereoselective dimerization of arylacetylenes and optical and electrochemical studies of (E)-1,3-enynes.” Advanced Synthesis and Catalysis, vol. 356, no. 11-12, Jul. 2014, pp. 2671-2678. https://onlinelibrary.wiley.com/doi/10.1002/adsc.201400062.
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