volume 357 issue 4 pages 753-760

Heterogeneous Gold-Catalyzed Selective Reductive Transformation of Quinolines with Formic Acid

Publication typeJournal Article
Publication date2015-02-06
scimago Q1
wos Q1
SJR0.930
CiteScore8.0
Impact factor4.0
ISSN16154150, 16154169
General Chemistry
Abstract
Single phase rutile titania supported gold nanoparticles (Au/TiO2-R) are found to be efficient and versatile catalysts for chemo- and regioselective transfer hydrogenation of quinoline derivatives to 1,2,3,4-tetrahydroquinolines (THQs) using formic acid (FA) as a safe and convenient hydrogen source under mild conditions. The activity and chemoselectivity of the Au/TiO2-R catalyst towards THQs is excellent, with a substrate to catalyst ratio (S/C) of 1000 being feasible. Furthermore, a straightforward and selective route to N-formyltetrahydroquinolines (FTHQ) directly from quinoline compounds and FA by one-pot, gold-catalyzed reductive N-formylation protocol is also established.
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GOST |
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GOST Copy
Tao L. et al. Heterogeneous Gold-Catalyzed Selective Reductive Transformation of Quinolines with Formic Acid // Advanced Synthesis and Catalysis. 2015. Vol. 357. No. 4. pp. 753-760.
GOST all authors (up to 50) Copy
Tao L., Zhang Q., Li S. S., Liu X., Liu Y. M., Cao Y. Heterogeneous Gold-Catalyzed Selective Reductive Transformation of Quinolines with Formic Acid // Advanced Synthesis and Catalysis. 2015. Vol. 357. No. 4. pp. 753-760.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/adsc.201400721
UR - https://doi.org/10.1002/adsc.201400721
TI - Heterogeneous Gold-Catalyzed Selective Reductive Transformation of Quinolines with Formic Acid
T2 - Advanced Synthesis and Catalysis
AU - Tao, Lei
AU - Zhang, Qi
AU - Li, Shu Shuang
AU - Liu, Xiang
AU - Liu, Yong Mei
AU - Cao, Yong
PY - 2015
DA - 2015/02/06
PB - Wiley
SP - 753-760
IS - 4
VL - 357
SN - 1615-4150
SN - 1615-4169
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Tao,
author = {Lei Tao and Qi Zhang and Shu Shuang Li and Xiang Liu and Yong Mei Liu and Yong Cao},
title = {Heterogeneous Gold-Catalyzed Selective Reductive Transformation of Quinolines with Formic Acid},
journal = {Advanced Synthesis and Catalysis},
year = {2015},
volume = {357},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/adsc.201400721},
number = {4},
pages = {753--760},
doi = {10.1002/adsc.201400721}
}
MLA
Cite this
MLA Copy
Tao, Lei, et al. “Heterogeneous Gold-Catalyzed Selective Reductive Transformation of Quinolines with Formic Acid.” Advanced Synthesis and Catalysis, vol. 357, no. 4, Feb. 2015, pp. 753-760. https://doi.org/10.1002/adsc.201400721.