Recent Developments in Trifluoromethylation or Difluoroalkylation by Use of Difluorinated Phosphonium Salts
1
Department of Architecture and Environment; Chongqing Vocational Institute of Safety Technology, Wanzhou District; Chongqing People's Republic of China
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Publication type: Journal Article
Publication date: 2017-01-04
scimago Q1
wos Q1
SJR: 0.930
CiteScore: 8.0
Impact factor: 4.0
ISSN: 16154150, 16154169
General Chemistry
Abstract
Recent advances in trifluoromethylation or difluoroalkylation reactions by use of difluorinated phosphonium salts are summarized. In the presence of base, water, photocatalyst, fluoride or under the heating conditions, the difluorinated phosphonium salts can produce difluorocarbene, the CF2H radical or the trifluoromethyl anion, which are major intermediates for the difluoroalkylation or trifluoromethylation reaction and give moderate to excellent yields of the desired products in most cases.
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GOST
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Zhang C. Recent Developments in Trifluoromethylation or Difluoroalkylation by Use of Difluorinated Phosphonium Salts // Advanced Synthesis and Catalysis. 2017. Vol. 359. No. 3. pp. 372-383.
GOST all authors (up to 50)
Copy
Zhang C. Recent Developments in Trifluoromethylation or Difluoroalkylation by Use of Difluorinated Phosphonium Salts // Advanced Synthesis and Catalysis. 2017. Vol. 359. No. 3. pp. 372-383.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/adsc.201601011
UR - https://doi.org/10.1002/adsc.201601011
TI - Recent Developments in Trifluoromethylation or Difluoroalkylation by Use of Difluorinated Phosphonium Salts
T2 - Advanced Synthesis and Catalysis
AU - Zhang, Cai
PY - 2017
DA - 2017/01/04
PB - Wiley
SP - 372-383
IS - 3
VL - 359
SN - 1615-4150
SN - 1615-4169
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Zhang,
author = {Cai Zhang},
title = {Recent Developments in Trifluoromethylation or Difluoroalkylation by Use of Difluorinated Phosphonium Salts},
journal = {Advanced Synthesis and Catalysis},
year = {2017},
volume = {359},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/adsc.201601011},
number = {3},
pages = {372--383},
doi = {10.1002/adsc.201601011}
}
Cite this
MLA
Copy
Zhang, Cai. “Recent Developments in Trifluoromethylation or Difluoroalkylation by Use of Difluorinated Phosphonium Salts.” Advanced Synthesis and Catalysis, vol. 359, no. 3, Jan. 2017, pp. 372-383. https://doi.org/10.1002/adsc.201601011.