Advanced Synthesis and Catalysis, volume 363, issue 22, pages 5155-5161
Gold‐Catalyzed Intramolecular Tandem Cyclization of Alkynol‐Tethered Alkylidenecyclopropanes to Construct Naphthalene‐Fused Eight‐ to Eleven‐Membered Cyclic Ethers
Publication type: Journal Article
Publication date: 2021-10-26
Journal:
Advanced Synthesis and Catalysis
Q1
Q1
SJR: 1.020
CiteScore: 9.4
Impact factor: 4.4
ISSN: 16154150, 16154169
General Chemistry
Abstract
A gold-catalyzed intramolecular tandem cyclization of alkynol-tethered alkylidenecyclopropanes was reported in this paper, providing a synthetic route to access naphthalene-fused eight- to eleven-membered cyclic ether derivatives in moderate to good yields. On the basis of control experiments and DFT calculations, a reasonable reaction mechanism involving a gold carbene intermediate was proposed, which was formed via the 6-endo-dig enyne cyclization process.
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Tao L., Wei Yin 尹., Shi M. Gold‐Catalyzed Intramolecular Tandem Cyclization of Alkynol‐Tethered Alkylidenecyclopropanes to Construct Naphthalene‐Fused Eight‐ to Eleven‐Membered Cyclic Ethers // Advanced Synthesis and Catalysis. 2021. Vol. 363. No. 22. pp. 5155-5161.
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Tao L., Wei Yin 尹., Shi M. Gold‐Catalyzed Intramolecular Tandem Cyclization of Alkynol‐Tethered Alkylidenecyclopropanes to Construct Naphthalene‐Fused Eight‐ to Eleven‐Membered Cyclic Ethers // Advanced Synthesis and Catalysis. 2021. Vol. 363. No. 22. pp. 5155-5161.
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TY - JOUR
DO - 10.1002/adsc.202101095
UR - https://doi.org/10.1002/adsc.202101095
TI - Gold‐Catalyzed Intramolecular Tandem Cyclization of Alkynol‐Tethered Alkylidenecyclopropanes to Construct Naphthalene‐Fused Eight‐ to Eleven‐Membered Cyclic Ethers
T2 - Advanced Synthesis and Catalysis
AU - Tao, Leyi
AU - Wei Yin, 尹维
AU - Shi, Min
PY - 2021
DA - 2021/10/26
PB - Wiley
SP - 5155-5161
IS - 22
VL - 363
SN - 1615-4150
SN - 1615-4169
ER -
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@article{2021_Tao,
author = {Leyi Tao and 尹维 Wei Yin and Min Shi},
title = {Gold‐Catalyzed Intramolecular Tandem Cyclization of Alkynol‐Tethered Alkylidenecyclopropanes to Construct Naphthalene‐Fused Eight‐ to Eleven‐Membered Cyclic Ethers},
journal = {Advanced Synthesis and Catalysis},
year = {2021},
volume = {363},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/adsc.202101095},
number = {22},
pages = {5155--5161},
doi = {10.1002/adsc.202101095}
}
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Tao, Leyi, et al. “Gold‐Catalyzed Intramolecular Tandem Cyclization of Alkynol‐Tethered Alkylidenecyclopropanes to Construct Naphthalene‐Fused Eight‐ to Eleven‐Membered Cyclic Ethers.” Advanced Synthesis and Catalysis, vol. 363, no. 22, Oct. 2021, pp. 5155-5161. https://doi.org/10.1002/adsc.202101095.