Yttrium‐Catalyzed Intermolecular Anti‐Markovnikov Hydroamination and Sequential Intermolecular Hydroamination/Endocyclization of Vinylsilanes
Publication type: Journal Article
Publication date: 2023-11-14
scimago Q1
wos Q1
SJR: 0.930
CiteScore: 8.0
Impact factor: 4.0
ISSN: 16154150, 16154169
General Chemistry
Abstract
The intermolecular anti‐Markovnikov hydroamination of vinylsilanes was achieved utilizing five silyl‐substituted ortho‐terphenoxide yttrium complexes. The highest activity was observed for the most sterically encumbered triphenylsilyl‐substituted complex. Excellent activity and complete anti‐Markonikov selectivity were obtained for a variety of benzylic and aliphatic primary and secondary amines. Interestingly, the reaction with 2‐picolylamine produced the hydroaminoalkylation product rather than the hydroamination product. Reaction of dimethyldivinylsilane resulted in a range of 1,4‐azasilinanes via sequential hydroamination/endocyclization in good yields.
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8
Total citations:
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Citations from 2024:
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(100%)
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Polak L. H., Soltys J. B., Hultzsch K. C. Yttrium‐Catalyzed Intermolecular Anti‐Markovnikov Hydroamination and Sequential Intermolecular Hydroamination/Endocyclization of Vinylsilanes // Advanced Synthesis and Catalysis. 2023. Vol. 365. No. 23. pp. 4293-4302.
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Polak L. H., Soltys J. B., Hultzsch K. C. Yttrium‐Catalyzed Intermolecular Anti‐Markovnikov Hydroamination and Sequential Intermolecular Hydroamination/Endocyclization of Vinylsilanes // Advanced Synthesis and Catalysis. 2023. Vol. 365. No. 23. pp. 4293-4302.
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TY - JOUR
DO - 10.1002/adsc.202300862
UR - https://doi.org/10.1002/adsc.202300862
TI - Yttrium‐Catalyzed Intermolecular Anti‐Markovnikov Hydroamination and Sequential Intermolecular Hydroamination/Endocyclization of Vinylsilanes
T2 - Advanced Synthesis and Catalysis
AU - Polak, Lara H
AU - Soltys, John B.
AU - Hultzsch, Kai C.
PY - 2023
DA - 2023/11/14
PB - Wiley
SP - 4293-4302
IS - 23
VL - 365
SN - 1615-4150
SN - 1615-4169
ER -
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BibTex (up to 50 authors)
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@article{2023_Polak,
author = {Lara H Polak and John B. Soltys and Kai C. Hultzsch},
title = {Yttrium‐Catalyzed Intermolecular Anti‐Markovnikov Hydroamination and Sequential Intermolecular Hydroamination/Endocyclization of Vinylsilanes},
journal = {Advanced Synthesis and Catalysis},
year = {2023},
volume = {365},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/adsc.202300862},
number = {23},
pages = {4293--4302},
doi = {10.1002/adsc.202300862}
}
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MLA
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Polak, Lara H., et al. “Yttrium‐Catalyzed Intermolecular Anti‐Markovnikov Hydroamination and Sequential Intermolecular Hydroamination/Endocyclization of Vinylsilanes.” Advanced Synthesis and Catalysis, vol. 365, no. 23, Nov. 2023, pp. 4293-4302. https://doi.org/10.1002/adsc.202300862.