Cobalt‐catalyzed Intramolecular Cycloadditions of Alkenylidenecyclopropanes with Alkenes and Dienes

Publication type: Journal Article
Publication date: 2023-11-21
Wiley
scimago Q1
wos Q1
SJR: 0.930
CiteScore: 8.0
Impact factor: 4.0
ISSN: 16154150, 16154169
General Chemistry
Abstract

Low‐valent cobalt complexes equipped with phosphorous type of ligands can promote the intramolecular (3+2) cycloaddition of alkylidenecyclopropanes (ACPs) with alkenes and with allenes. Dienes can also be used as partners, but they afford seven‐membered cycloadducts. The reactions are fully diastereoselective and, in some cases, we also observed moderate enantioselectivities, especially when using chiral phosphite ligands.

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Da Concepción E. et al. Cobalt‐catalyzed Intramolecular Cycloadditions of Alkenylidenecyclopropanes with Alkenes and Dienes // Advanced Synthesis and Catalysis. 2023.
GOST all authors (up to 50) Copy
Da Concepción E., Fernández I., Mascareñas J. L., López F. Cobalt‐catalyzed Intramolecular Cycloadditions of Alkenylidenecyclopropanes with Alkenes and Dienes // Advanced Synthesis and Catalysis. 2023.
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TY - JOUR
DO - 10.1002/adsc.202301040
UR - https://doi.org/10.1002/adsc.202301040
TI - Cobalt‐catalyzed Intramolecular Cycloadditions of Alkenylidenecyclopropanes with Alkenes and Dienes
T2 - Advanced Synthesis and Catalysis
AU - Da Concepción, Eduardo
AU - Fernández, Israel
AU - Mascareñas, José L
AU - López, Fernando
PY - 2023
DA - 2023/11/21
PB - Wiley
SN - 1615-4150
SN - 1615-4169
ER -
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Cite this
BibTex (up to 50 authors) Copy
@article{2023_Da Concepción,
author = {Eduardo Da Concepción and Israel Fernández and José L Mascareñas and Fernando López},
title = {Cobalt‐catalyzed Intramolecular Cycloadditions of Alkenylidenecyclopropanes with Alkenes and Dienes},
journal = {Advanced Synthesis and Catalysis},
year = {2023},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/adsc.202301040},
doi = {10.1002/adsc.202301040}
}