Advanced Energy Materials, volume 12, issue 19, pages 2200244

Diffusion Limited Current Density: A Watershed in Electrodeposition of Lithium Metal Anode

Xu Xieyu ¹

Jiao Xingxing ^{2, 3}

Kapitanova Olesya O. ^{1, 2, 3}

Wang Jialin ⁴

Volkov Valentyn S. ²

Liu Yangyang ^{2, 3}

Xiong Shizhao ⁵

Hide authors affiliations Show authors affiliations: 5 affiliations

Department of Materials Science Lomonosov Moscow State University Leninskie gory 1 Moscow 119991 Russia |

Center for Photonics and 2D Materials Moscow Institute of Physics and Technology 9 Institutskiy per., Moscow Region Dolgoprudny 141701 Russia |

Autonomous Noncommercial Organization “ID&AS: Inter‐Disciplinary & Advanced Studies Center” Moscow 127495 Russia |

⁴

State Key Laboratory for Mechanical Behavior of Materials Xi'an Jiaotong University Xi'an 710049 P. R. China |

⁵

Department of Physics Chalmers University of Technology Göteborg SE 412 96 Sweden |

Publication type: Journal Article

Publication date: 2022-04-07

Wiley

Journal: Advanced Energy Materials

Quartile SCImago

Quartile WOS

Impact factor: 27.8

ISSN: 16146832, 16146840

DOI: 10.1002/aenm.202200244

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General Materials Science

Renewable Energy, Sustainability and the Environment

Abstract

Lithium metal is considered to be a promising anode material for high‐energy‐density rechargeable batteries because of its high theoretical capacity and low reduction potential. Nevertheless, the practical application of Li anodes is challenged by poor cyclic performance and potential safety hazards, which are attributed to non‐uniform electrodeposition of Li metal during charging. Herein, diffusion limited current density (DLCD), one of the critical fundamental parameters that govern the electrochemical reaction process, is investigated as the threshold of current density for electrodeposition of Li. The visualization of the concentration field and distribution of Faradic current density reveal how uniform electrodeposition of Li metal anodes can be obtained when the applied current density is below the DLCD of the related electrochemical system. Moreover, the electrodeposition of Li metal within broken solid electrolyte interphases preferentially occurs at the crack spots that are caused by the non‐uniform electrodeposition of Li metal. This post‐electrodeposition leads to more consumption of active Li when the applied current density is greater than the DLCD. Therefore, lowering the applied current density or increasing the DLCD are proposed as directions for developing advanced strategies to realize uniform electrodeposition of Li metal and stable interfaces, aiming to accelerate the practical application of state‐of‐the‐art Li metal batteries.

By date By citations

Citations by journals

	1 2 3 4
Journal of Energy Chemistry	Journal of Energy Chemistry, 4, 9.09% Journal of Energy Chemistry 4 publications, 9.09%
ACS applied materials & interfaces	ACS applied materials & interfaces, 4, 9.09% ACS applied materials & interfaces 4 publications, 9.09%
Advanced Energy Materials	Advanced Energy Materials, 2, 4.55% Advanced Energy Materials 2 publications, 4.55%
Chemical Engineering Journal	Chemical Engineering Journal, 2, 4.55% Chemical Engineering Journal 2 publications, 4.55%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 2, 4.55% Angewandte Chemie - International Edition 2 publications, 4.55%
Angewandte Chemie	Angewandte Chemie, 2, 4.55% Angewandte Chemie 2 publications, 4.55%
ACS Energy Letters	ACS Energy Letters, 2, 4.55% ACS Energy Letters 2 publications, 4.55%
Nano-Micro Letters	Nano-Micro Letters, 2, 4.55% Nano-Micro Letters 2 publications, 4.55%
ACS Applied Energy Materials	ACS Applied Energy Materials, 1, 2.27% ACS Applied Energy Materials 1 publication, 2.27%
Functional Materials Letters	Functional Materials Letters, 1, 2.27% Functional Materials Letters 1 publication, 2.27%
Inorganics	Inorganics, 1, 2.27% Inorganics 1 publication, 2.27%
Frontiers of Chemical Science and Engineering	Frontiers of Chemical Science and Engineering, 1, 2.27% Frontiers of Chemical Science and Engineering 1 publication, 2.27%
Composites Communications	Composites Communications, 1, 2.27% Composites Communications 1 publication, 2.27%
Electrochimica Acta	Electrochimica Acta, 1, 2.27% Electrochimica Acta 1 publication, 2.27%
Applied Surface Science	Applied Surface Science, 1, 2.27% Applied Surface Science 1 publication, 2.27%
Interdisciplinary Materials	Interdisciplinary Materials, 1, 2.27% Interdisciplinary Materials 1 publication, 2.27%
Advanced Materials	Advanced Materials, 1, 2.27% Advanced Materials 1 publication, 2.27%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 1, 2.27% Journal of Materials Chemistry A 1 publication, 2.27%
Energy Material Advances	Energy Material Advances, 1, 2.27% Energy Material Advances 1 publication, 2.27%
Energy Advances	Energy Advances, 1, 2.27% Energy Advances 1 publication, 2.27%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 1, 2.27% Journal of the Electrochemical Society 1 publication, 2.27%
Journal of the European Ceramic Society	Journal of the European Ceramic Society, 1, 2.27% Journal of the European Ceramic Society 1 publication, 2.27%
Advanced Science	Advanced Science, 1, 2.27% Advanced Science 1 publication, 2.27%
Journal of Power Sources	Journal of Power Sources, 1, 2.27% Journal of Power Sources 1 publication, 2.27%
New Carbon Materials	New Carbon Materials, 1, 2.27% New Carbon Materials 1 publication, 2.27%
Journal of Solid State Electrochemistry	Journal of Solid State Electrochemistry, 1, 2.27% Journal of Solid State Electrochemistry 1 publication, 2.27%
Solid State Ionics	Solid State Ionics, 1, 2.27% Solid State Ionics 1 publication, 2.27%
Journal of Energy Storage	Journal of Energy Storage, 1, 2.27% Journal of Energy Storage 1 publication, 2.27%
Nano Letters	Nano Letters, 1, 2.27% Nano Letters 1 publication, 2.27%
Advanced Functional Materials	Advanced Functional Materials, 1, 2.27% Advanced Functional Materials 1 publication, 2.27%
	1 2 3 4

Citations by publishers

	2 4 6 8 10 12 14
Elsevier	Elsevier, 14, 31.82% Elsevier 14 publications, 31.82%
Wiley	Wiley, 11, 25% Wiley 11 publications, 25%
American Chemical Society (ACS)	American Chemical Society (ACS), 8, 18.18% American Chemical Society (ACS) 8 publications, 18.18%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 3, 6.82% Royal Society of Chemistry (RSC) 3 publications, 6.82%
Springer Nature	Springer Nature, 3, 6.82% Springer Nature 3 publications, 6.82%
World Scientific	World Scientific, 1, 2.27% World Scientific 1 publication, 2.27%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 2.27% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 2.27%
Higher Education Press	Higher Education Press, 1, 2.27% Higher Education Press 1 publication, 2.27%
American Association for the Advancement of Science (AAAS)	American Association for the Advancement of Science (AAAS), 1, 2.27% American Association for the Advancement of Science (AAAS) 1 publication, 2.27%
The Electrochemical Society	The Electrochemical Society, 1, 2.27% The Electrochemical Society 1 publication, 2.27%
	2 4 6 8 10 12 14

We do not take into account publications that without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
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Xu X. et al. Diffusion Limited Current Density: A Watershed in Electrodeposition of Lithium Metal Anode // Advanced Energy Materials. 2022. Vol. 12. No. 19. p. 2200244.

GOST all authors (up to 50) Copy

Xu X., Jiao X., Kapitanova O. O., Wang J., Volkov V. S., Liu Y., Xiong S. Diffusion Limited Current Density: A Watershed in Electrodeposition of Lithium Metal Anode // Advanced Energy Materials. 2022. Vol. 12. No. 19. p. 2200244.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/aenm.202200244

UR - https://doi.org/10.1002%2Faenm.202200244

TI - Diffusion Limited Current Density: A Watershed in Electrodeposition of Lithium Metal Anode

T2 - Advanced Energy Materials

AU - Xu, Xieyu

AU - Jiao, Xingxing

AU - Kapitanova, Olesya O.

AU - Volkov, Valentyn S.

AU - Liu, Yangyang

AU - Xiong, Shizhao

AU - Wang, Jialin

PY - 2022

DA - 2022/04/07 00:00:00

PB - Wiley

SP - 2200244

IS - 19

VL - 12

SN - 1614-6832

SN - 1614-6840

ER -

BibTex |

Cite this

BibTex Copy

@article{2022_Xu,

author = {Xieyu Xu and Xingxing Jiao and Olesya O. Kapitanova and Valentyn S. Volkov and Yangyang Liu and Shizhao Xiong and Jialin Wang},

title = {Diffusion Limited Current Density: A Watershed in Electrodeposition of Lithium Metal Anode},

journal = {Advanced Energy Materials},

year = {2022},

volume = {12},

publisher = {Wiley},

month = {apr},

url = {https://doi.org/10.1002%2Faenm.202200244},

number = {19},

pages = {2200244},

doi = {10.1002/aenm.202200244}

}

MLA

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MLA Copy

Xu, Xieyu, et al. “Diffusion Limited Current Density: A Watershed in Electrodeposition of Lithium Metal Anode.” Advanced Energy Materials, vol. 12, no. 19, Apr. 2022, p. 2200244. https://doi.org/10.1002%2Faenm.202200244.

Found error?

Publisher

Wiley

Journal

Advanced Energy Materials

Quartile SCImago

Quartile WOS

Impact factor

27.8

ISSN

16146832 (Print)
16146840 (Electronic)

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