Advanced Energy Materials, volume 13, issue 35
Prospective Application, Mechanism, and Deficiency of Lithium Bis(oxalate)Borate as the Electrolyte Additive for Lithium‐Batteries
JIANING LI
1
,
Jianzhong Yang
2
,
Zhaoqi Ji
3
,
Min Su
4
,
Huijing Li
1
,
Yanchao Wu
1
,
Xin Su
5
,
Zhengcheng Zhang
6
2
R&D center Shenzhen ORI Technology Company Limited Shenzhen 518000 China
|
4
R&D Center Wanxiang A123 Systems Corp Hangzhou 311215 China
|
Publication type: Journal Article
Publication date: 2023-07-30
Journal:
Advanced Energy Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 27.8
ISSN: 16146832, 16146840
General Materials Science
Renewable Energy, Sustainability and the Environment
Abstract
Lithium bis(oxalate)borate (LiBOB) is one of the most common film‐forming electrolyte additives used in lithium ion batteries (LIBs), since it can form a dense boron‐containing polymer as a solid electrolyte interlayer (or cathode electrolyte interlayer) in order to isolate the electrode material from the electrolyte and prevent side reactions. LiBOB can serve as HF scavenger to maintain the structural integrity of electrodes via avoiding the transition metal dissolution caused by HF attack. LiBOB also can react with LiPF6 to generate lithium difluoro (oxalate)borate (LiDFOB) that can be further used as a clean‐up agent for reactive oxygen radicals. This article lists the application of LiBOB in high capacity and high voltage cathode materials, and also reviews the working mechanisms of LiBOB used in these materials to improve the performance of LIBs. Finally, it presents the current shortcomings of LiBOB and strategies to overcome these. This article is expected to provide useful insights for employing LiBOB as a feasible method of dealing with the difficulty of running high capacity LIBs stably under high voltage.
Top-30
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1 publication, 7.14%
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1 publication, 7.14%
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1 publication, 7.14%
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Citations by publishers
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Elsevier
6 publications, 42.86%
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Wiley
4 publications, 28.57%
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American Chemical Society (ACS)
2 publications, 14.29%
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Springer Nature
1 publication, 7.14%
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American Institute of Physics (AIP)
1 publication, 7.14%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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LI J. et al. Prospective Application, Mechanism, and Deficiency of Lithium Bis(oxalate)Borate as the Electrolyte Additive for Lithium‐Batteries // Advanced Energy Materials. 2023. Vol. 13. No. 35.
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LI J., Yang J., Ji Z., Su M., Li H., Wu Y., Su X., Zhang Z. Prospective Application, Mechanism, and Deficiency of Lithium Bis(oxalate)Borate as the Electrolyte Additive for Lithium‐Batteries // Advanced Energy Materials. 2023. Vol. 13. No. 35.
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TY - JOUR
DO - 10.1002/aenm.202301422
UR - https://doi.org/10.1002/aenm.202301422
TI - Prospective Application, Mechanism, and Deficiency of Lithium Bis(oxalate)Borate as the Electrolyte Additive for Lithium‐Batteries
T2 - Advanced Energy Materials
AU - LI, JIANING
AU - Yang, Jianzhong
AU - Ji, Zhaoqi
AU - Su, Min
AU - Li, Huijing
AU - Wu, Yanchao
AU - Su, Xin
AU - Zhang, Zhengcheng
PY - 2023
DA - 2023/07/30 00:00:00
PB - Wiley
IS - 35
VL - 13
SN - 1614-6832
SN - 1614-6840
ER -
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@article{2023_LI,
author = {JIANING LI and Jianzhong Yang and Zhaoqi Ji and Min Su and Huijing Li and Yanchao Wu and Xin Su and Zhengcheng Zhang},
title = {Prospective Application, Mechanism, and Deficiency of Lithium Bis(oxalate)Borate as the Electrolyte Additive for Lithium‐Batteries},
journal = {Advanced Energy Materials},
year = {2023},
volume = {13},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/aenm.202301422},
number = {35},
doi = {10.1002/aenm.202301422}
}