Advanced Energy Materials, volume 13, issue 38

Polymer‐Based Solid‐State Electrolytes for High‐Energy‐Density Lithium‐Ion Batteries – Review

Xiao Lu ¹

Yumei Wang ²

Xu Xiaoyu ^{1, 2}

Binggong Yan ³

Tian Wu ⁴

Li Lu ^{1, 2}

Hide authors affiliations Show authors affiliations: 4 affiliations

Department of Mechanical Engineering National University of Singapore Singapore 117575 Singapore |

National University of Singapore (Chongqing) Research Institute Chongqing 401123 China |

Fujian Key Laboratory of Special Energy Manufacturing Huaqiao University Xiamen 361021 China |

⁴

Institute of Materials Research and Engineering Hubei University of Education Wuhan 430205 China |

Publication type: Journal Article

Publication date: 2023-08-29

Wiley

Journal: Advanced Energy Materials

Quartile SCImago

Quartile WOS

Impact factor: 27.8

ISSN: 16146832, 16146840

DOI: 10.1002/aenm.202301746

Copy DOI

General Materials Science

Renewable Energy, Sustainability and the Environment

Abstract

Portable electronic devices and electric vehicles have become indispensable in daily life and caused an increasing demand for high‐performance lithium‐ion batteries (LIBs) with high‐energy‐density. This work compares the intrinsic characteristics and Li⁺ conduction mechanisms of various electrolytes, aiming at emphasizing their suitability for high‐energy‐density LIBs. Among all electrolytes, polymer‐based solid‐state electrolytes (SSEs) are the most promising candidates, as they demonstrate the most comprehensive properties. The advantages and disadvantages of commonly used polymer matrix materials of SSEs are discussed, along with typical approaches to address their limitations. As significant issues for high‐energy‐density and cycle stability, the development related to the cathode/electrolyte interfacial contact and wetting, interfacial electrochemical compatibility, and interfacial Li⁺ conduction in LIBs employing polymer‐based SSEs, as well as the anode/electrolyte interfacial chemical stability and lithium dendrite suppression are comprehensively reviewed and analyzed. Finally, perspectives on future research directions for developing high‐energy‐density LIBs are highlighted building upon the existing literature.

By date By citations

Top-30

Citations by journals

	1 2 3 4
Advanced Energy Materials	Advanced Energy Materials, 4, 8.89% Advanced Energy Materials 4 publications, 8.89%
Advanced Functional Materials	Advanced Functional Materials, 3, 6.67% Advanced Functional Materials 3 publications, 6.67%
Materials Today Sustainability	Materials Today Sustainability, 2, 4.44% Materials Today Sustainability 2 publications, 4.44%
Journal of Energy Chemistry	Journal of Energy Chemistry, 2, 4.44% Journal of Energy Chemistry 2 publications, 4.44%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 2, 4.44% Journal of Alloys and Compounds 2 publications, 4.44%
ACS Applied Energy Materials	ACS Applied Energy Materials, 2, 4.44% ACS Applied Energy Materials 2 publications, 4.44%
Advanced Materials	Advanced Materials, 2, 4.44% Advanced Materials 2 publications, 4.44%
ChemSusChem	ChemSusChem, 1, 2.22% ChemSusChem 1 publication, 2.22%
Renewable and Sustainable Energy Reviews	Renewable and Sustainable Energy Reviews, 1, 2.22% Renewable and Sustainable Energy Reviews 1 publication, 2.22%
Battery Energy	Battery Energy, 1, 2.22% Battery Energy 1 publication, 2.22%
Nano Research	Nano Research, 1, 2.22% Nano Research 1 publication, 2.22%
Journal of Solid State Electrochemistry	Journal of Solid State Electrochemistry, 1, 2.22% Journal of Solid State Electrochemistry 1 publication, 2.22%
Energy & Fuels	Energy & Fuels, 1, 2.22% Energy & Fuels 1 publication, 2.22%
eTransportation	eTransportation, 1, 2.22% eTransportation 1 publication, 2.22%
Chem & Bio Engineering	Chem & Bio Engineering, 1, 2.22% Chem & Bio Engineering 1 publication, 2.22%
Science China Materials	Science China Materials, 1, 2.22% Science China Materials 1 publication, 2.22%
Chemical Engineering Journal	Chemical Engineering Journal, 1, 2.22% Chemical Engineering Journal 1 publication, 2.22%
ACS Sustainable Chemistry and Engineering	ACS Sustainable Chemistry and Engineering, 1, 2.22% ACS Sustainable Chemistry and Engineering 1 publication, 2.22%
Journal of Polymer Research	Journal of Polymer Research, 1, 2.22% Journal of Polymer Research 1 publication, 2.22%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 1, 2.22% Journal of Colloid and Interface Science 1 publication, 2.22%
ChemElectroChem	ChemElectroChem, 1, 2.22% ChemElectroChem 1 publication, 2.22%
ACS applied materials & interfaces	ACS applied materials & interfaces, 1, 2.22% ACS applied materials & interfaces 1 publication, 2.22%
Energy Storage Materials	Energy Storage Materials, 1, 2.22% Energy Storage Materials 1 publication, 2.22%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 1, 2.22% Angewandte Chemie - International Edition 1 publication, 2.22%
Angewandte Chemie	Angewandte Chemie, 1, 2.22% Angewandte Chemie 1 publication, 2.22%
Small Structures	Small Structures, 1, 2.22% Small Structures 1 publication, 2.22%
ACS Materials Letters	ACS Materials Letters, 1, 2.22% ACS Materials Letters 1 publication, 2.22%
Journal of Electroanalytical Chemistry	Journal of Electroanalytical Chemistry, 1, 2.22% Journal of Electroanalytical Chemistry 1 publication, 2.22%
Nano-Micro Letters	Nano-Micro Letters, 1, 2.22% Nano-Micro Letters 1 publication, 2.22%
Journal of Polymer Science	Journal of Polymer Science, 1, 2.22% Journal of Polymer Science 1 publication, 2.22%
	1 2 3 4

Citations by publishers

	2 4 6 8 10 12 14 16
Wiley	Wiley, 16, 35.56% Wiley 16 publications, 35.56%
Elsevier	Elsevier, 15, 33.33% Elsevier 15 publications, 33.33%
American Chemical Society (ACS)	American Chemical Society (ACS), 7, 15.56% American Chemical Society (ACS) 7 publications, 15.56%
Springer Nature	Springer Nature, 5, 11.11% Springer Nature 5 publications, 11.11%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 2.22% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 2.22%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 2.22% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 2.22%
	2 4 6 8 10 12 14 16

We do not take into account publications without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2023,2024,2025],"ids":[0,0,0],"codes":[0,0,0],"imageUrls":["","",""],"datasets":[{"label":"Citations number","data":[1,43,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6"],"percentage":["2.22","95.56","2.22"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Advanced Energy Materials","Advanced Functional Materials","Materials Today Sustainability","Journal of Energy Chemistry","Journal of Alloys and Compounds","ACS Applied Energy Materials","Advanced Materials","ChemSusChem","Renewable and Sustainable Energy Reviews","Battery Energy","Nano Research","Journal of Solid State Electrochemistry","Energy & Fuels","eTransportation","Chem & Bio Engineering","Science China Materials","Chemical Engineering Journal","ACS Sustainable Chemistry and Engineering","Journal of Polymer Research","Journal of Colloid and Interface Science","ChemElectroChem","ACS applied materials & interfaces","Energy Storage Materials","Angewandte Chemie - International Edition","Angewandte Chemie","Small Structures","ACS Materials Letters","Journal of Electroanalytical Chemistry","Nano-Micro Letters","Journal of Polymer Science"],"ids":[22475,7715,10882,20653,4015,6419,25159,6896,17453,29981,12211,10804,10347,25487,64114,23382,16275,18886,22642,24202,22483,1458,3858,19215,25450,27248,13131,22454,7765,25771],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp"],"datasets":[{"label":"","data":[4,3,2,2,2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[8.89,6.67,4.44,4.44,4.44,4.44,4.44,2.22,2.22,2.22,2.22,2.22,2.22,2.22,2.22,2.22,2.22,2.22,2.22,2.22,2.22,2.22,2.22,2.22,2.22,2.22,2.22,2.22,2.22,2.22],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Wiley","Elsevier","American Chemical Society (ACS)","Springer Nature","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii","Multidisciplinary Digital Publishing Institute (MDPI)"],"ids":[11,17,40,8,9422,202],"codes":[0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp"],"datasets":[{"label":"","data":[16,15,7,5,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[35.56,33.33,15.56,11.11,2.22,2.22],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2023,2024,2025],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0],"percentage":["0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0],"percentage":["0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,4,1],"percentage":["0","8.89","2.22"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[1,36,0],"percentage":["2.22","80","0"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,3,0],"percentage":["0","6.67","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2023,2024,2025],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,1,0],"percentage":["0","2.22","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,1,0],"percentage":["0","2.22","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,3,1],"percentage":["0","6.67","2.22"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[1,35,0],"percentage":["2.22","77.78","0"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,3,0],"percentage":["0","6.67","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Lu X. et al. Polymer‐Based Solid‐State Electrolytes for High‐Energy‐Density Lithium‐Ion Batteries – Review // Advanced Energy Materials. 2023. Vol. 13. No. 38.

GOST all authors (up to 50) Copy

Lu X., Wang Y., Xu Xiaoyu, Yan B., Wu T., Lu L. Polymer‐Based Solid‐State Electrolytes for High‐Energy‐Density Lithium‐Ion Batteries – Review // Advanced Energy Materials. 2023. Vol. 13. No. 38.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1002/aenm.202301746

UR - https://doi.org/10.1002/aenm.202301746

TI - Polymer‐Based Solid‐State Electrolytes for High‐Energy‐Density Lithium‐Ion Batteries – Review

T2 - Advanced Energy Materials

AU - Lu, Xiao

AU - Wang, Yumei

AU - Xu Xiaoyu

AU - Yan, Binggong

AU - Wu, Tian

AU - Lu, Li

PY - 2023

DA - 2023/08/29 00:00:00

PB - Wiley

IS - 38

VL - 13

SN - 1614-6832

SN - 1614-6840

ER -

BibTex

Cite this

BibTex Copy

@article{2023_Lu,

author = {Xiao Lu and Yumei Wang and Xu Xiaoyu and Binggong Yan and Tian Wu and Li Lu},

title = {Polymer‐Based Solid‐State Electrolytes for High‐Energy‐Density Lithium‐Ion Batteries – Review},

journal = {Advanced Energy Materials},

year = {2023},

volume = {13},

publisher = {Wiley},

month = {aug},

url = {https://doi.org/10.1002/aenm.202301746},

number = {38},

doi = {10.1002/aenm.202301746}

}

Found error?

Publisher

Wiley

Journal

Advanced Energy Materials

Quartile SCImago

Quartile WOS

Impact factor

27.8

ISSN

16146832 (Print)
16146840 (Electronic)

Profiles

Lu, Li Hsuan