Open Access
Advanced Energy and Sustainability Research, volume 4, issue 12
The Influence of Polyethylene Oxide Degradation in Polymer‐Based Electrolytes for NMC and Lithium Metal Batteries
Lukas Herbers
1
,
Jaroslav Minář
1
,
Silvan Stuckenberg
1
,
Verena Küpers
1
,
Debbie Berghus
1
,
Sascha Nowak
1
,
Martin Winter
1, 2
,
Peter Bieker
2
Publication type: Journal Article
Publication date: 2023-10-06
Quartile SCImago
— Quartile WOS
—
Impact factor: 5.6
ISSN: 26999412, 26999412
General Medicine
Abstract
A multilayered ternary solid polymer electrolyte (TSPE) is presented. First, the influence of polyethylene oxide degradation on cell failure, development of subsequent volatile degradation products, and cell impedance is analyzed. The low electrochemical stability window/oxidative stability (≥3.8 V) results in side‐chain oxidation and loss of active material. Subsequently, electrolyte stability is improved and a thin‐film (≤50 μm) TSPE with three functional layers is developed to match the wide‐ranging electrolyte requirements toward Li metal anodes and different cathode materials like LiNi0.6Mn0.2Co0.2O2 and LiFePO4 (NCM622, LFP). The high‐voltage stability of ≥4.75 V makes the TSPE a promising candidate in high‐voltage applications. Because of high Coulombic efficiencies in NMC622‖Li metal (99.7%) and LFP‖Li metal (99.9%) cells, the presented electrolyte enables stable long‐term cycling with great capacity retention of 86% and 94%, respectively. The temperature stability of >300 °C and the capability to prevent high surface area Li and dendrite formation (even at an areal capacity utilization of >40 mAh cm−2) contribute to high safety under a wide range of conditions.
Top-30
Citations by journals
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1
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ACS applied materials & interfaces
1 publication, 33.33%
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ACS Sustainable Chemistry and Engineering
1 publication, 33.33%
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Russian Chemical Reviews
1 publication, 33.33%
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1
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Citations by publishers
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1
2
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American Chemical Society (ACS)
2 publications, 66.67%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 33.33%
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1
2
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Herbers L. et al. The Influence of Polyethylene Oxide Degradation in Polymer‐Based Electrolytes for NMC and Lithium Metal Batteries // Advanced Energy and Sustainability Research. 2023. Vol. 4. No. 12.
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Herbers L., Minář J., Stuckenberg S., Küpers V., Berghus D., Nowak S., Winter M., Bieker P. The Influence of Polyethylene Oxide Degradation in Polymer‐Based Electrolytes for NMC and Lithium Metal Batteries // Advanced Energy and Sustainability Research. 2023. Vol. 4. No. 12.
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TY - JOUR
DO - 10.1002/aesr.202300153
UR - https://doi.org/10.1002/aesr.202300153
TI - The Influence of Polyethylene Oxide Degradation in Polymer‐Based Electrolytes for NMC and Lithium Metal Batteries
T2 - Advanced Energy and Sustainability Research
AU - Herbers, Lukas
AU - Minář, Jaroslav
AU - Stuckenberg, Silvan
AU - Küpers, Verena
AU - Berghus, Debbie
AU - Nowak, Sascha
AU - Winter, Martin
AU - Bieker, Peter
PY - 2023
DA - 2023/10/06 00:00:00
PB - Wiley
IS - 12
VL - 4
SN - 2699-9412
SN - 2699-9412
ER -
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@article{2023_Herbers,
author = {Lukas Herbers and Jaroslav Minář and Silvan Stuckenberg and Verena Küpers and Debbie Berghus and Sascha Nowak and Martin Winter and Peter Bieker},
title = {The Influence of Polyethylene Oxide Degradation in Polymer‐Based Electrolytes for NMC and Lithium Metal Batteries},
journal = {Advanced Energy and Sustainability Research},
year = {2023},
volume = {4},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/aesr.202300153},
number = {12},
doi = {10.1002/aesr.202300153}
}