Wiley
Asian Journal of Organic Chemistry
,  том 4 ,  издание 11 ,  страницы 1301-1307

A Route to 1-Alkenylphosphine Derivatives via the Zr-Catalyzed Reaction of 1-Alkynylphosphines with Triethylaluminum

Тип публикации: Journal Article
Дата публикации: 2015-09-09
Wiley
SCImago Q3
WOS Q2
БС1
SJR: 0.394
CiteScore: 5
Impact factor: 2.7
ISSN: 21935807, 21935815
Organic Chemistry
Краткое описание
The Cp2ZrCl2-catalyzed reaction of 1-alkynyldiphenylphosphines with Et3Al, followed by deuterolysis and oxidation, affords substituted (E)-(but-1-en-1-yl-1,4-d2)diphenylphosphine oxides. It is suggested that the reaction proceeds through the formation of intermediate aluminacyclopent-2-enes. Substituted (E)-but-1-en-1-yldiphenylphosphine sulfides and 4-butyl-5-(diphenylphosphoryl)-1-phenyl-2,3-dihydrophosphole 1-oxide were prepared by reacting intermediate organoaluminum compounds with S8 and PhPCl2. The mechanism of the cycloalumination of 1-alkynylphosphines is proposed.
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Ramazanov I. R. et al. A Route to 1-Alkenylphosphine Derivatives via the Zr-Catalyzed Reaction of 1-Alkynylphosphines with Triethylaluminum // Asian Journal of Organic Chemistry. 2015. Vol. 4. No. 11. pp. 1301-1307.
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Ramazanov I. R., Kadikova R. N., Saitova Z. R., Dzhemilev U. M. A Route to 1-Alkenylphosphine Derivatives via the Zr-Catalyzed Reaction of 1-Alkynylphosphines with Triethylaluminum // Asian Journal of Organic Chemistry. 2015. Vol. 4. No. 11. pp. 1301-1307.
RIS |
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TY - JOUR
DO - 10.1002/ajoc.201500274
UR - https://doi.org/10.1002/ajoc.201500274
TI - A Route to 1-Alkenylphosphine Derivatives via the Zr-Catalyzed Reaction of 1-Alkynylphosphines with Triethylaluminum
T2 - Asian Journal of Organic Chemistry
AU - Ramazanov, Ilfir R
AU - Kadikova, Rita N.
AU - Saitova, Zukhra R
AU - Dzhemilev, Usein M
PY - 2015
DA - 2015/09/09
PB - Wiley
SP - 1301-1307
IS - 11
VL - 4
SN - 2193-5807
SN - 2193-5815
ER -
BibTex |
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@article{2015_Ramazanov,
author = {Ilfir R Ramazanov and Rita N. Kadikova and Zukhra R Saitova and Usein M Dzhemilev},
title = {A Route to 1-Alkenylphosphine Derivatives via the Zr-Catalyzed Reaction of 1-Alkynylphosphines with Triethylaluminum},
journal = {Asian Journal of Organic Chemistry},
year = {2015},
volume = {4},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/ajoc.201500274},
number = {11},
pages = {1301--1307},
doi = {10.1002/ajoc.201500274}
}
MLA
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Ramazanov, Ilfir R., et al. “A Route to 1-Alkenylphosphine Derivatives via the Zr-Catalyzed Reaction of 1-Alkynylphosphines with Triethylaluminum.” Asian Journal of Organic Chemistry, vol. 4, no. 11, Sep. 2015, pp. 1301-1307. https://doi.org/10.1002/ajoc.201500274.
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