Angewandte Chemie, volume 118, issue 25, pages 4288-4291
A Snapshot of P4 Tetrahedron Opening: Rh- and Ir-Mediated Activation of White Phosphorus
Publication type: Journal Article
Publication date: 2006-06-19
General Medicine
Abstract
P und P gesellt sich gern: Weißer Phosphor reagiert mit [M(dppm)2]OTf (M=Rh, Ir; dppm=PPh2CH2PPh2) zu [M(dppm)(Ph2PCH2PPh2PPPP)]OTf. Dabei entsteht durch Bildung einer P-P-Bindung zwischen einer PPh2-Gruppe von dppm und einem aktivierten P4-Molekül ein trihaptischer „P5“-Ligand (P grün, M rot, C weiß; Phenylgruppen nicht gezeigt). In-situ-31P-NMR-Studien sprechen für einen Reaktionsweg, der über eine Dimetallzwischenstufe verläuft.
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Yakhvarov D. et al. A Snapshot of P4 Tetrahedron Opening: Rh- and Ir-Mediated Activation of White Phosphorus // Angewandte Chemie. 2006. Vol. 118. No. 25. pp. 4288-4291.
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Yakhvarov D., Barbaro P., Gonsalvi L., Mañas Carpio S., Midollini S., Orlandini A., Peruzzini M., Sinyashin O., Zanobini F. A Snapshot of P4 Tetrahedron Opening: Rh- and Ir-Mediated Activation of White Phosphorus // Angewandte Chemie. 2006. Vol. 118. No. 25. pp. 4288-4291.
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TY - JOUR
DO - 10.1002/ange.200601048
UR - https://doi.org/10.1002/ange.200601048
TI - A Snapshot of P4 Tetrahedron Opening: Rh- and Ir-Mediated Activation of White Phosphorus
T2 - Angewandte Chemie
AU - Yakhvarov, Dmitry
AU - Barbaro, Pierluigi
AU - Gonsalvi, Luca
AU - Mañas Carpio, Sonia
AU - Midollini, Stefano
AU - Orlandini, Annabella
AU - Peruzzini, Maurizio
AU - Sinyashin, Oleg
AU - Zanobini, Fabrizio
PY - 2006
DA - 2006/06/19
PB - Wiley
SP - 4288-4291
IS - 25
VL - 118
SN - 0044-8249
SN - 1521-3757
ER -
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@article{2006_Yakhvarov,
author = {Dmitry Yakhvarov and Pierluigi Barbaro and Luca Gonsalvi and Sonia Mañas Carpio and Stefano Midollini and Annabella Orlandini and Maurizio Peruzzini and Oleg Sinyashin and Fabrizio Zanobini},
title = {A Snapshot of P4 Tetrahedron Opening: Rh- and Ir-Mediated Activation of White Phosphorus},
journal = {Angewandte Chemie},
year = {2006},
volume = {118},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/ange.200601048},
number = {25},
pages = {4288--4291},
doi = {10.1002/ange.200601048}
}
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Yakhvarov, Dmitry, et al. “A Snapshot of P4 Tetrahedron Opening: Rh- and Ir-Mediated Activation of White Phosphorus.” Angewandte Chemie, vol. 118, no. 25, Jun. 2006, pp. 4288-4291. https://doi.org/10.1002/ange.200601048.