Cobalt-Catalyzed Addition of Arylzinc Reagents to Alkynes to Form ortho-Alkenylarylzinc Species through 1,4-Cobalt Migration
Publication type: Journal Article
Publication date: 2012-08-24
General Medicine
Abstract
Ein Cobalt-Xantphos-Komplex katalysiert die Addition eines Arylzinkreagens an ein nichtaktiviertes internes Alkin. Die Reaktion beinhaltet wahrscheinlich die Insertion des Alkins in eine Arylcobaltspezies mit anschließender 1,4-Wanderung des Cobaltfragments von der Vinyl- zur Aryleinheit, gefolgt von Transmetallierung mit dem Arylzinkreagens. Die resultierende ortho-Alkenylaryl-Zinkspezies reagiert mit Elektrophilen zu in 2-Stellung funktionalisierten 1-Alkenyl-Arenen.
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42
Total citations:
42
Citations from 2024:
1
(2%)
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Tan B. H., Dong J., Yoshikai N. Cobalt-Catalyzed Addition of Arylzinc Reagents to Alkynes to Form ortho-Alkenylarylzinc Species through 1,4-Cobalt Migration // Angewandte Chemie. 2012. Vol. 124. No. 38. pp. 9748-9752.
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Tan B. H., Dong J., Yoshikai N. Cobalt-Catalyzed Addition of Arylzinc Reagents to Alkynes to Form ortho-Alkenylarylzinc Species through 1,4-Cobalt Migration // Angewandte Chemie. 2012. Vol. 124. No. 38. pp. 9748-9752.
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RIS
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TY - JOUR
DO - 10.1002/ange.201204388
UR - https://doi.org/10.1002/ange.201204388
TI - Cobalt-Catalyzed Addition of Arylzinc Reagents to Alkynes to Form ortho-Alkenylarylzinc Species through 1,4-Cobalt Migration
T2 - Angewandte Chemie
AU - Tan, Boon Hong
AU - Dong, Jinghua
AU - Yoshikai, Naohiko
PY - 2012
DA - 2012/08/24
PB - Wiley
SP - 9748-9752
IS - 38
VL - 124
SN - 0044-8249
SN - 1521-3757
ER -
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BibTex (up to 50 authors)
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@article{2012_Tan,
author = {Boon Hong Tan and Jinghua Dong and Naohiko Yoshikai},
title = {Cobalt-Catalyzed Addition of Arylzinc Reagents to Alkynes to Form ortho-Alkenylarylzinc Species through 1,4-Cobalt Migration},
journal = {Angewandte Chemie},
year = {2012},
volume = {124},
publisher = {Wiley},
month = {aug},
url = {https://doi.org/10.1002/ange.201204388},
number = {38},
pages = {9748--9752},
doi = {10.1002/ange.201204388}
}
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MLA
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Tan, Boon Hong, et al. “Cobalt-Catalyzed Addition of Arylzinc Reagents to Alkynes to Form ortho-Alkenylarylzinc Species through 1,4-Cobalt Migration.” Angewandte Chemie, vol. 124, no. 38, Aug. 2012, pp. 9748-9752. https://doi.org/10.1002/ange.201204388.