Angewandte Chemie - International Edition, volume 48, issue 1, pages 34-46

Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents

Publication typeJournal Article
Publication date2008-12-18
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor16.6
ISSN14337851, 15213773
General Chemistry
Catalysis
Abstract

Classical protocols for carbonyl allylation, propargylation and vinylation typically rely upon the use of preformed allyl metal, allenyl metal and vinyl metal reagents, respectively, mandating stoichiometric generation of metallic byproducts. Through transfer hydrogenative CC coupling, however, carbonyl addition may be achieved from the aldehyde or alcohol oxidation level in the absence of stoichiometric organometallic reagents or metallic reductants. Here, we review transfer hydrogenative methods for carbonyl addition, which encompass the first catalytic protocols enabling direct CH functionalization of alcohols.

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GOST |
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GOST Copy
Bower J. E. et al. Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents // Angewandte Chemie - International Edition. 2008. Vol. 48. No. 1. pp. 34-46.
GOST all authors (up to 50) Copy
Bower J. E., Kim I. S., Patman R. L., Krische M. J. Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents // Angewandte Chemie - International Edition. 2008. Vol. 48. No. 1. pp. 34-46.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/anie.200802938
UR - https://onlinelibrary.wiley.com/doi/10.1002/anie.200802938
TI - Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents
T2 - Angewandte Chemie - International Edition
AU - Bower, John Eric
AU - Kim, In Su
AU - Patman, Ryan L
AU - Krische, Michael J
PY - 2008
DA - 2008/12/18 00:00:00
PB - Wiley
SP - 34-46
IS - 1
VL - 48
PMID - 19040235
SN - 1433-7851
SN - 1521-3773
ER -
BibTex |
Cite this
BibTex Copy
@article{2008_Bower,
author = {John Eric Bower and In Su Kim and Ryan L Patman and Michael J Krische},
title = {Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents},
journal = {Angewandte Chemie - International Edition},
year = {2008},
volume = {48},
publisher = {Wiley},
month = {dec},
url = {https://onlinelibrary.wiley.com/doi/10.1002/anie.200802938},
number = {1},
pages = {34--46},
doi = {10.1002/anie.200802938}
}
MLA
Cite this
MLA Copy
Bower, John Eric, et al. “Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents.” Angewandte Chemie - International Edition, vol. 48, no. 1, Dec. 2008, pp. 34-46. https://onlinelibrary.wiley.com/doi/10.1002/anie.200802938.
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