volume 51 issue 46 pages 11527-11530

Threshold Ionization of Cobaltocene: The Metallocene Molecule Revealing Zero Kinetic Energy States

Publication typeJournal Article
Publication date2012-09-13
scimago Q1
wos Q1
SJR5.550
CiteScore27.6
Impact factor16.9
ISSN14337851, 15213773
General Chemistry
Catalysis
Abstract
Playing it cool: The mass-analyzed threshold ionization (MATI) spectrum of jet-cooled cobaltocene shows a surprisingly rich vibronic structure which provides high-resolution adiabatic (Iad.) and vertical (Ivert.) ionization energies of the neutral molecule, as well as vibrational frequencies of the gas-phase cation. The spectrum is indicative of both Jahn–Teller (JT) and pseudo-Jahn–Teller (PJT) activity in the 19-electron [Cp2Co] sandwich complex.
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Ketkov S. Y., Selzle H. L. Threshold Ionization of Cobaltocene: The Metallocene Molecule Revealing Zero Kinetic Energy States // Angewandte Chemie - International Edition. 2012. Vol. 51. No. 46. pp. 11527-11530.
GOST all authors (up to 50) Copy
Ketkov S. Y., Selzle H. L. Threshold Ionization of Cobaltocene: The Metallocene Molecule Revealing Zero Kinetic Energy States // Angewandte Chemie - International Edition. 2012. Vol. 51. No. 46. pp. 11527-11530.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/anie.201205164
UR - https://doi.org/10.1002/anie.201205164
TI - Threshold Ionization of Cobaltocene: The Metallocene Molecule Revealing Zero Kinetic Energy States
T2 - Angewandte Chemie - International Edition
AU - Ketkov, Sergey Yu.
AU - Selzle, Heinrich L.
PY - 2012
DA - 2012/09/13
PB - Wiley
SP - 11527-11530
IS - 46
VL - 51
PMID - 22976947
SN - 1433-7851
SN - 1521-3773
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2012_Ketkov,
author = {Sergey Yu. Ketkov and Heinrich L. Selzle},
title = {Threshold Ionization of Cobaltocene: The Metallocene Molecule Revealing Zero Kinetic Energy States},
journal = {Angewandte Chemie - International Edition},
year = {2012},
volume = {51},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/anie.201205164},
number = {46},
pages = {11527--11530},
doi = {10.1002/anie.201205164}
}
MLA
Cite this
MLA Copy
Ketkov, Sergey Yu., and Heinrich L. Selzle. “Threshold Ionization of Cobaltocene: The Metallocene Molecule Revealing Zero Kinetic Energy States.” Angewandte Chemie - International Edition, vol. 51, no. 46, Sep. 2012, pp. 11527-11530. https://doi.org/10.1002/anie.201205164.