Angewandte Chemie - International Edition, volume 54, issue 5, pages 1504-1507
Magnetic Memory in an Isotopically Enriched and Magnetically Isolated Mononuclear Dysprosium Complex
Publication type: Journal Article
Publication date: 2014-12-08
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
The influence of nuclear spin on the magnetic hysteresis of a single-molecule is evidenced. Isotopically enriched Dy(III) complexes are synthesized and an isotopic dependence of their magnetic relaxation is observed. This approach is coupled with tuning of the molecular environment through dilution in an amorphous or an isomorphous diamagnetic matrix. The combination of these approaches leads to a dramatic enhancement of the magnetic memory of the molecule. This general recipe can be efficient for rational optimization of single-molecule magnets (SMMs), and provides an important step for their integration into molecule-based devices.
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Pointillart F. et al. Magnetic Memory in an Isotopically Enriched and Magnetically Isolated Mononuclear Dysprosium Complex // Angewandte Chemie - International Edition. 2014. Vol. 54. No. 5. pp. 1504-1507.
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Pointillart F., Bernot K., Golhen S., Le Guennic B., Guizouarn T., Ouahab L., Cador O. Magnetic Memory in an Isotopically Enriched and Magnetically Isolated Mononuclear Dysprosium Complex // Angewandte Chemie - International Edition. 2014. Vol. 54. No. 5. pp. 1504-1507.
Cite this
RIS
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TY - JOUR
DO - 10.1002/anie.201409887
UR - https://doi.org/10.1002/anie.201409887
TI - Magnetic Memory in an Isotopically Enriched and Magnetically Isolated Mononuclear Dysprosium Complex
T2 - Angewandte Chemie - International Edition
AU - Pointillart, Fabrice
AU - Bernot, Kevin
AU - Golhen, Stéphane
AU - Le Guennic, Boris
AU - Guizouarn, Thierry
AU - Ouahab, Lahcène
AU - Cador, Olivier
PY - 2014
DA - 2014/12/08
PB - Wiley
SP - 1504-1507
IS - 5
VL - 54
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex
Copy
@article{2014_Pointillart,
author = {Fabrice Pointillart and Kevin Bernot and Stéphane Golhen and Boris Le Guennic and Thierry Guizouarn and Lahcène Ouahab and Olivier Cador},
title = {Magnetic Memory in an Isotopically Enriched and Magnetically Isolated Mononuclear Dysprosium Complex},
journal = {Angewandte Chemie - International Edition},
year = {2014},
volume = {54},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/anie.201409887},
number = {5},
pages = {1504--1507},
doi = {10.1002/anie.201409887}
}
Cite this
MLA
Copy
Pointillart, Fabrice, et al. “Magnetic Memory in an Isotopically Enriched and Magnetically Isolated Mononuclear Dysprosium Complex.” Angewandte Chemie - International Edition, vol. 54, no. 5, Dec. 2014, pp. 1504-1507. https://doi.org/10.1002/anie.201409887.