Poly( N ‐isopropylacrylamide) Phase Diagrams: Fifty Years of Research
Publication type: Journal Article
Publication date: 2015-11-27
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
26612195
General Chemistry
Catalysis
Abstract
In 1968, Heskins and Guillet published the first systematic study of the phase diagram of poly(N-isopropylacrylamide) (PNIPAM), at the time a "young polymer" first synthesized in 1956. Since then, PNIPAM became the leading member of the growing families of thermoresponsive polymers and of stimuli-responsive, "smart" polymers in general. Its thermal response is unanimously attributed to its phase behavior. Yet, in spite of 50 years of research, a coherent quantitative picture remains elusive. In this Review we survey the reported phase diagrams, discuss the differences and comment on theoretical ideas regarding their possible origins. We aim to alert the PNIPAM community to open questions in this reputably mature domain.
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Total citations:
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Halperin A. et al. Poly( N ‐isopropylacrylamide) Phase Diagrams: Fifty Years of Research // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 51. pp. 15342-15367.
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Halperin A., Kröger M., Winnik F. M. Poly( N ‐isopropylacrylamide) Phase Diagrams: Fifty Years of Research // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 51. pp. 15342-15367.
Cite this
RIS
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TY - JOUR
DO - 10.1002/anie.201506663
UR - https://doi.org/10.1002/anie.201506663
TI - Poly( N ‐isopropylacrylamide) Phase Diagrams: Fifty Years of Research
T2 - Angewandte Chemie - International Edition
AU - Halperin, Avraham
AU - Kröger, Martin
AU - Winnik, Francoise M.
PY - 2015
DA - 2015/11/27
PB - Wiley
SP - 15342-15367
IS - 51
VL - 54
PMID - 26612195
SN - 1433-7851
SN - 1521-3773
ER -
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BibTex (up to 50 authors)
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@article{2015_Halperin,
author = {Avraham Halperin and Martin Kröger and Francoise M. Winnik},
title = {Poly( N ‐isopropylacrylamide) Phase Diagrams: Fifty Years of Research},
journal = {Angewandte Chemie - International Edition},
year = {2015},
volume = {54},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/anie.201506663},
number = {51},
pages = {15342--15367},
doi = {10.1002/anie.201506663}
}
Cite this
MLA
Copy
Halperin, Avraham, et al. “Poly( N ‐isopropylacrylamide) Phase Diagrams: Fifty Years of Research.” Angewandte Chemie - International Edition, vol. 54, no. 51, Nov. 2015, pp. 15342-15367. https://doi.org/10.1002/anie.201506663.