A Free-Radical-Promoted Stereospecific Decarboxylative Silylation of α,β-Unsaturated Acids with Silanes
Publication type: Journal Article
Publication date: 2015-11-19
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
26582425
General Chemistry
Catalysis
Abstract
A stereospecific decarboxylative silylation of acrylic and propiolic acids with silanes was developed. This reaction represents the first example of decarboxylative C-Si bond formation and provides an efficient and convenient approach to various synthetically useful alkenyl and alkynyl organosilicon compounds through the reaction of α,β-unsaturated acids with silanes. Spin-trapping and EPR experiments support a radical addition/elimination process.
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Metrics
140
Total citations:
140
Citations from 2024:
21
(15%)
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MLA
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GOST
Copy
Zhang L., Hang Z., Liu Z. A Free-Radical-Promoted Stereospecific Decarboxylative Silylation of α,β-Unsaturated Acids with Silanes // Angewandte Chemie - International Edition. 2015. Vol. 55. No. 1. pp. 236-239.
GOST all authors (up to 50)
Copy
Zhang L., Hang Z., Liu Z. A Free-Radical-Promoted Stereospecific Decarboxylative Silylation of α,β-Unsaturated Acids with Silanes // Angewandte Chemie - International Edition. 2015. Vol. 55. No. 1. pp. 236-239.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201509537
UR - https://doi.org/10.1002/anie.201509537
TI - A Free-Radical-Promoted Stereospecific Decarboxylative Silylation of α,β-Unsaturated Acids with Silanes
T2 - Angewandte Chemie - International Edition
AU - Zhang, Lizhi
AU - Hang, Zhaojia
AU - Liu, Zhongquan
PY - 2015
DA - 2015/11/19
PB - Wiley
SP - 236-239
IS - 1
VL - 55
PMID - 26582425
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Zhang,
author = {Lizhi Zhang and Zhaojia Hang and Zhongquan Liu},
title = {A Free-Radical-Promoted Stereospecific Decarboxylative Silylation of α,β-Unsaturated Acids with Silanes},
journal = {Angewandte Chemie - International Edition},
year = {2015},
volume = {55},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/anie.201509537},
number = {1},
pages = {236--239},
doi = {10.1002/anie.201509537}
}
Cite this
MLA
Copy
Zhang, Lizhi, et al. “A Free-Radical-Promoted Stereospecific Decarboxylative Silylation of α,β-Unsaturated Acids with Silanes.” Angewandte Chemie - International Edition, vol. 55, no. 1, Nov. 2015, pp. 236-239. https://doi.org/10.1002/anie.201509537.