Angewandte Chemie - International Edition, volume 55, issue 38, pages 11572-11576
Chemoselective Alternating Copolymerization of Limonene Dioxide and Carbon Dioxide: A New Highly Functional Aliphatic Epoxy Polycarbonate
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Polymer Technology Group Eindhoven B.V. (PTG/e B.V.); P.O. Box 6284 5600 HG Eindhoven The Netherlands
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3
DSM Coating Resins; Ceintuurbaan 5 8022 AW Zwolle The Netherlands
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Publication type: Journal Article
Publication date: 2016-08-16
Q1
Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
The alternating copolymerization of biorenewable limonene dioxide with carbon dioxide (CO2 ) catalyzed by a zinc β-diiminate complex is reported. The chemoselective reaction results in linear amorphous polycarbonates that carry pendent methyloxiranes and exhibit glass transition temperatures (Tg ) up to 135 °C. These polycarbonates can be efficiently modified by thiols or carboxylic acids in combination with lithium hydroxide or tetrabutylphosphonium bromide as catalysts, respectively, without destruction of the main chain. Moreover, polycarbonates bearing pendent cyclic carbonates can be quantitatively prepared by CO2 insertion catalyzed by lithium bromide.
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GOST
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Li C. et al. Chemoselective Alternating Copolymerization of Limonene Dioxide and Carbon Dioxide: A New Highly Functional Aliphatic Epoxy Polycarbonate // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 38. pp. 11572-11576.
GOST all authors (up to 50)
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Li C., Sablong R. J., Koning C. E. Chemoselective Alternating Copolymerization of Limonene Dioxide and Carbon Dioxide: A New Highly Functional Aliphatic Epoxy Polycarbonate // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 38. pp. 11572-11576.
Cite this
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TY - JOUR
DO - 10.1002/anie.201604674
UR - https://doi.org/10.1002/anie.201604674
TI - Chemoselective Alternating Copolymerization of Limonene Dioxide and Carbon Dioxide: A New Highly Functional Aliphatic Epoxy Polycarbonate
T2 - Angewandte Chemie - International Edition
AU - Li, Chunliang
AU - Sablong, Rafaël J
AU - Koning, Cor E
PY - 2016
DA - 2016/08/16
PB - Wiley
SP - 11572-11576
IS - 38
VL - 55
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
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@article{2016_Li,
author = {Chunliang Li and Rafaël J Sablong and Cor E Koning},
title = {Chemoselective Alternating Copolymerization of Limonene Dioxide and Carbon Dioxide: A New Highly Functional Aliphatic Epoxy Polycarbonate},
journal = {Angewandte Chemie - International Edition},
year = {2016},
volume = {55},
publisher = {Wiley},
month = {aug},
url = {https://doi.org/10.1002/anie.201604674},
number = {38},
pages = {11572--11576},
doi = {10.1002/anie.201604674}
}
Cite this
MLA
Copy
Li, Chunliang, et al. “Chemoselective Alternating Copolymerization of Limonene Dioxide and Carbon Dioxide: A New Highly Functional Aliphatic Epoxy Polycarbonate.” Angewandte Chemie - International Edition, vol. 55, no. 38, Aug. 2016, pp. 11572-11576. https://doi.org/10.1002/anie.201604674.