Angewandte Chemie - International Edition, volume 55, issue 48, pages 14952-14957

Thiolate-Mediated Photoinduced Synthesis of Ultrafine Ag2 S Quantum Dots from Silver Nanoparticles.

Yitao Cao ^{1, 2}

Wei Geng ³

Run Shi ^{1, 2}

LU SHANG ¹

Geoffrey I. N. Waterhouse ⁴

Limin Liu ³

Li-Zhu Wu ¹

Chen-Ho Tung ¹

Yadong Yin ⁵

Tierui Zhang ¹

Hide authors affiliations Show authors affiliations: 5 affiliations

key Laboratory of Photochemical Conversion and Optoelectronic Materials; Technical Institute of Physics and Chemistry; Chinese Academy of Sciences; Beijing 100190 China |

University of Chinese Academy of Sciences; Beijing 100049 China |

Beijing Computational Science Research Center; Beijing 100084 China |

⁴

School of Chemical Sciences; the University of Auckland; Auckland 1142 New Zealand |

⁵

Department of Chemistry; University of California; Riverside California 92521 USA |

Publication type: Journal Article

Publication date: 2016-10-27

Wiley

Journal: Angewandte Chemie - International Edition

Quartile SCImago

Quartile WOS

Impact factor: 16.6

ISSN: 14337851, 15213773

DOI: 10.1002/anie.201608019

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General Chemistry

Catalysis

Abstract

Photoinduced syntheses offer significant advantages over conventional thermal strategies, including improved control over reaction kinetics and low synthesis temperatures, affording nanoparticles with nontrivial and thermodynamically unstable structures. However, the photoinduced syntheses of non-metallic nanocrystalline products (such as metal sulfides) have not yet been reported. Herein, we demonstrate the first photoinduced synthesis of ultrafine (sub-2 nm) Ag2 S quantum dots (QDs) from Ag nanoparticles at 10 °C. By thorough investigation of the mechanism for the transformation, a fundamental link was established between the intrinsic structures of the molecular intermediates and the final Ag2 S products. Our results confirm the viability of low-temperature photochemical approaches in metal sulfide synthesis, and demonstrate a new rule which could be followed in it.

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Cao Y. et al. Thiolate-Mediated Photoinduced Synthesis of Ultrafine Ag2 S Quantum Dots from Silver Nanoparticles. // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 48. pp. 14952-14957.

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Cao Y., Geng W., Shi R., SHANG L., Waterhouse G. I. N., Liu L., Wu L., Tung C., Yin Y., Zhang T. Thiolate-Mediated Photoinduced Synthesis of Ultrafine Ag2 S Quantum Dots from Silver Nanoparticles. // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 48. pp. 14952-14957.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/anie.201608019

UR - https://doi.org/10.1002/anie.201608019

TI - Thiolate-Mediated Photoinduced Synthesis of Ultrafine Ag2 S Quantum Dots from Silver Nanoparticles.

T2 - Angewandte Chemie - International Edition

AU - Cao, Yitao

AU - Geng, Wei

AU - SHANG, LU

AU - Liu, Limin

AU - Zhang, Tierui

AU - Shi, Run

AU - Waterhouse, Geoffrey I. N.

AU - Wu, Li-Zhu

AU - Tung, Chen-Ho

AU - Yin, Yadong

PY - 2016

DA - 2016/10/27 00:00:00

PB - Wiley

SP - 14952-14957

IS - 48

VL - 55

SN - 1433-7851

SN - 1521-3773

ER -

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BibTex Copy

@article{2016_Cao,

author = {Yitao Cao and Wei Geng and LU SHANG and Limin Liu and Tierui Zhang and Run Shi and Geoffrey I. N. Waterhouse and Li-Zhu Wu and Chen-Ho Tung and Yadong Yin},

title = {Thiolate-Mediated Photoinduced Synthesis of Ultrafine Ag2 S Quantum Dots from Silver Nanoparticles.},

journal = {Angewandte Chemie - International Edition},

year = {2016},

volume = {55},

publisher = {Wiley},

month = {oct},

url = {https://doi.org/10.1002/anie.201608019},

number = {48},

pages = {14952--14957},

doi = {10.1002/anie.201608019}

}

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Cao, Yitao, et al. “Thiolate-Mediated Photoinduced Synthesis of Ultrafine Ag2 S Quantum Dots from Silver Nanoparticles..” Angewandte Chemie - International Edition, vol. 55, no. 48, Oct. 2016, pp. 14952-14957. https://doi.org/10.1002/anie.201608019.

Found error?

Publisher

Wiley

Journal

Angewandte Chemie - International Edition

Quartile SCImago

Quartile WOS

Impact factor

16.6

ISSN

14337851 (Print)
15213773 (Electronic)