Angewandte Chemie - International Edition

, volume 56 , issue 9 , pages 2403-2407

Synthesis of C₇₀ -Based Fluorophores through Sequential Functionalization to Form Isomerically Pure Multiadducts

Ning Lou ¹

Yanbang Li ¹

Liangbing Gan ^{1, 2}

Hide authors affiliations Show authors affiliations: 2 affiliations

Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering; Peking University; Beijing 100871 China

Peking University

Beijing National Laboratory for Molecular Sciences

State Key Laboratory of Organometallic Chemistry; Shanghai Institute of Organic Chemistry; Shanghai 200032 China |

Publication type: Journal Article

Publication date: 2017-01-27

Wiley

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR: 5.550

CiteScore: 27.6

Impact factor: 16.9

ISSN: 14337851, 15213773

DOI: 10.1002/anie.201612054

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PubMed ID: 28128516

General Chemistry

Catalysis

Abstract

Selective addition to the C70 cage divides its π-conjugated system into various smaller π-conjugated systems with enhanced fluorescent properties. Key reactions include chlorination, methoxylation, ozonation, and Bingel or Bingel-Hirsch reactions. The maximum emission wavelength of the C70 multiadducts ranges from 450 to 655 nm. Among the C70 multiadducts, C70 (OMe)8 (C(COOEt)2 )3 showed the highest quantum yield (ΦF =0.18) and the largest Δ[λmax (emission)- λmax (absorption)] (402 nm), with maximum emission at 655 nm.

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Malkin Nikita

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7 publications, 13 citations

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Lomonosov Moscow State University

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Lou N. et al. Synthesis of C70 -Based Fluorophores through Sequential Functionalization to Form Isomerically Pure Multiadducts // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 9. pp. 2403-2407.

GOST all authors (up to 50) Copy

Lou N., Li Y., Gan L. Synthesis of C70 -Based Fluorophores through Sequential Functionalization to Form Isomerically Pure Multiadducts // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 9. pp. 2403-2407.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/anie.201612054

UR - https://doi.org/10.1002/anie.201612054

TI - Synthesis of C70 -Based Fluorophores through Sequential Functionalization to Form Isomerically Pure Multiadducts

T2 - Angewandte Chemie - International Edition

AU - Lou, Ning

AU - Li, Yanbang

AU - Gan, Liangbing

PY - 2017

DA - 2017/01/27

PB - Wiley

SP - 2403-2407

IS - 9

VL - 56

PMID - 28128516

SN - 1433-7851

SN - 1521-3773

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2017_Lou,

author = {Ning Lou and Yanbang Li and Liangbing Gan},

title = {Synthesis of C70 -Based Fluorophores through Sequential Functionalization to Form Isomerically Pure Multiadducts},

journal = {Angewandte Chemie - International Edition},

year = {2017},

volume = {56},

publisher = {Wiley},

month = {jan},

url = {https://doi.org/10.1002/anie.201612054},

number = {9},

pages = {2403--2407},

doi = {10.1002/anie.201612054}

}

MLA

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MLA Copy

Lou, Ning, et al. “Synthesis of C70 -Based Fluorophores through Sequential Functionalization to Form Isomerically Pure Multiadducts.” Angewandte Chemie - International Edition, vol. 56, no. 9, Jan. 2017, pp. 2403-2407. https://doi.org/10.1002/anie.201612054.

Publisher

Wiley

Journal

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR

5.550

CiteScore

27.6

Impact factor

16.9

ISSN

14337851 (Print)

15213773 (Electronic)