Angewandte Chemie - International Edition, volume 56, issue 48, pages 15241-15245
Hydrogen Peroxide Insular Dodecameric and Pentameric Clusters in Peroxosolvate Structures
Lev Ovadia
2
,
Prikhodchenko Petr V.
1, 2
,
Publication type: Journal Article
Publication date: 2017-10-19
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
Peroxosolvates of 2-aminonicotinic acid (I) and lidocaine N-oxide (II) including the largest insular hydrogen peroxide clusters were isolated and their crystal structures were determined by single-crystal X-ray diffraction. An unprecedented dodecameric hydrogen peroxide insular cluster was found in I. An unusual cross-like pentameric cluster was observed in the structure of II. The topology of the (H2 O2 )12 assembly was never observed for small-molecule clusters. In I and II new double and triple cross-orientational disorders of H2 O2 were found. Cluster II is the first example of a peroxosolvate crystal structure containing H2 O2 molecules with a homoleptic hydrogen peroxide environment. In II, a hydrogen bond between an H2 O2 molecule and a peptide group -CONH⋅⋅⋅O2 H2 was observed for the first time.
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1 publication, 4.55%
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Citations by publishers
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Royal Society of Chemistry (RSC)
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9 publications, 40.91%
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3 publications, 13.64%
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Elsevier
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3 publications, 13.64%
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3 publications, 13.64%
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American Chemical Society (ACS)
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2 publications, 9.09%
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International Union of Crystallography (IUCr)
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1 publication, 4.55%
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Walter de Gruyter
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Walter de Gruyter
1 publication, 4.55%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Grishanov D. A. et al. Hydrogen Peroxide Insular Dodecameric and Pentameric Clusters in Peroxosolvate Structures // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 48. pp. 15241-15245.
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Grishanov D. A., Navasardyan M. A., Medvedev A. G., Lev O., Prikhodchenko P. V., Churakov A. V. Hydrogen Peroxide Insular Dodecameric and Pentameric Clusters in Peroxosolvate Structures // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 48. pp. 15241-15245.
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TY - JOUR
DO - 10.1002/anie.201709699
UR - https://doi.org/10.1002%2Fanie.201709699
TI - Hydrogen Peroxide Insular Dodecameric and Pentameric Clusters in Peroxosolvate Structures
T2 - Angewandte Chemie - International Edition
AU - Grishanov, Dmitry A
AU - Navasardyan, Mger A.
AU - Medvedev, Alexander G.
AU - Lev, Ovadia
AU - Prikhodchenko, Petr V.
AU - Churakov, Andrei V.
PY - 2017
DA - 2017/10/19 00:00:00
PB - Wiley
SP - 15241-15245
IS - 48
VL - 56
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2017_Grishanov,
author = {Dmitry A Grishanov and Mger A. Navasardyan and Alexander G. Medvedev and Ovadia Lev and Petr V. Prikhodchenko and Andrei V. Churakov},
title = {Hydrogen Peroxide Insular Dodecameric and Pentameric Clusters in Peroxosolvate Structures},
journal = {Angewandte Chemie - International Edition},
year = {2017},
volume = {56},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002%2Fanie.201709699},
number = {48},
pages = {15241--15245},
doi = {10.1002/anie.201709699}
}
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Grishanov, Dmitry A., et al. “Hydrogen Peroxide Insular Dodecameric and Pentameric Clusters in Peroxosolvate Structures.” Angewandte Chemie - International Edition, vol. 56, no. 48, Oct. 2017, pp. 15241-15245. https://doi.org/10.1002%2Fanie.201709699.