Angewandte Chemie - International Edition, volume 57, issue 12, pages 3212-3216
Direct Observation of an Imidoylnitrene: Photochemical Formation of PhC(=NMe)−N and Me−N from 1-Methyl-5-phenyltetrazole
2
Institut Pluridisciplinaire de Recherche sur l'Environnement et les Matériaux; Université de Pau et des Pays de l'Adour; 64000 Pau France
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Publication type: Journal Article
Publication date: 2018-02-21
Quartile SCImago
Q1
Quartile WOS
Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
The imidoylnitrene 8, N-methyl-C-phenylimidoylnitrene, has been generated by laser photolysis of 1-methyl-5-phenyltetrazole 6 at 5 K and characterized by its ESR spectrum (|D/hc|=0.9602, |E/hc|=0.0144 cm-1 ). In addition, the triplet excited states of 6 and of 2-methyl-5-phenyltetrazole 11 were also observed by ESR spectroscopy in the 5 K matrices (6: |D/hc|=0.123 cm-1 , E/hc=0.0065 cm-1 , 11: |D/hc|=0.126 cm-1 , |E/hc|=0.0056 cm-1 ). The imidoylnitrene 8 is unstable both thermally (disappearing at 80 K) and photochemically (disappearing on continued irradiation at 266 nm). Methyl(phenyl)carbodiimide is the end product of photolysis.
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Abe M. et al. Direct Observation of an Imidoylnitrene: Photochemical Formation of PhC(=NMe)−N and Me−N from 1-Methyl-5-phenyltetrazole // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 12. pp. 3212-3216.
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Abe M., Bégué D., Santos Silva H., Dargelos A., Wentrup C. Direct Observation of an Imidoylnitrene: Photochemical Formation of PhC(=NMe)−N and Me−N from 1-Methyl-5-phenyltetrazole // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 12. pp. 3212-3216.
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RIS
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TY - JOUR
DO - 10.1002/anie.201712689
UR - https://doi.org/10.1002/anie.201712689
TI - Direct Observation of an Imidoylnitrene: Photochemical Formation of PhC(=NMe)−N and Me−N from 1-Methyl-5-phenyltetrazole
T2 - Angewandte Chemie - International Edition
AU - Dargelos, Alain
AU - Abe, Manabu
AU - Bégué, Didier
AU - Santos Silva, H
AU - Wentrup, Curt
PY - 2018
DA - 2018/02/21
PB - Wiley
SP - 3212-3216
IS - 12
VL - 57
SN - 1433-7851
SN - 1521-3773
ER -
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BibTex
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@article{2018_Abe,
author = {Alain Dargelos and Manabu Abe and Didier Bégué and H Santos Silva and Curt Wentrup},
title = {Direct Observation of an Imidoylnitrene: Photochemical Formation of PhC(=NMe)−N and Me−N from 1-Methyl-5-phenyltetrazole},
journal = {Angewandte Chemie - International Edition},
year = {2018},
volume = {57},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/anie.201712689},
number = {12},
pages = {3212--3216},
doi = {10.1002/anie.201712689}
}
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MLA
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Abe, Manabu, et al. “Direct Observation of an Imidoylnitrene: Photochemical Formation of PhC(=NMe)−N and Me−N from 1-Methyl-5-phenyltetrazole.” Angewandte Chemie - International Edition, vol. 57, no. 12, Feb. 2018, pp. 3212-3216. https://doi.org/10.1002/anie.201712689.