Me 3 Si−SiMe 2 [ o CON( i Pr) 2 −C 6 H 4 ]: An Unsymmetrical Disilane Reagent for Regio‐ and Stereoselective Bis‐Silylation of Alkynes
Publication type: Journal Article
Publication date: 2018-03-12
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
29442434
General Chemistry
Catalysis
Abstract
The air-stable unsymmetrical disilane Me3 Si-SiMe2 [oCON(iPr)2 C6 H4 ] has been developed for bis-silylation of alkynes. This reagent tolerates a range of functional groups, providing Z-vinyl disilanes in high yields. It is proposed that the phenyl-ring-tethered amide group directs oxidative addition of Pd0 into the Si-Si bond, which might facilitate formation of a six-membered Pd cycle, generating products with good to excellent regioselectivity.
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Total citations:
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Citations from 2024:
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(16.66%)
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GOST
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Xiao P. et al. Me 3 Si−SiMe 2 [ o CON( i Pr) 2 −C 6 H 4 ]: An Unsymmetrical Disilane Reagent for Regio‐ and Stereoselective Bis‐Silylation of Alkynes // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 17. pp. 4769-4773.
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Xiao P., Cao Y., Gui Y., Gao L., Song Z. Me 3 Si−SiMe 2 [ o CON( i Pr) 2 −C 6 H 4 ]: An Unsymmetrical Disilane Reagent for Regio‐ and Stereoselective Bis‐Silylation of Alkynes // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 17. pp. 4769-4773.
Cite this
RIS
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TY - JOUR
DO - 10.1002/anie.201800513
UR - https://doi.org/10.1002/anie.201800513
TI - Me 3 Si−SiMe 2 [ o CON( i Pr) 2 −C 6 H 4 ]: An Unsymmetrical Disilane Reagent for Regio‐ and Stereoselective Bis‐Silylation of Alkynes
T2 - Angewandte Chemie - International Edition
AU - Xiao, Peihong
AU - Cao, Yanjun
AU - Gui, Yingying
AU - Gao, Lu
AU - Song, Zhenlei
PY - 2018
DA - 2018/03/12
PB - Wiley
SP - 4769-4773
IS - 17
VL - 57
PMID - 29442434
SN - 1433-7851
SN - 1521-3773
ER -
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BibTex (up to 50 authors)
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@article{2018_Xiao,
author = {Peihong Xiao and Yanjun Cao and Yingying Gui and Lu Gao and Zhenlei Song},
title = {Me 3 Si−SiMe 2 [ o CON( i Pr) 2 −C 6 H 4 ]: An Unsymmetrical Disilane Reagent for Regio‐ and Stereoselective Bis‐Silylation of Alkynes},
journal = {Angewandte Chemie - International Edition},
year = {2018},
volume = {57},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/anie.201800513},
number = {17},
pages = {4769--4773},
doi = {10.1002/anie.201800513}
}
Cite this
MLA
Copy
Xiao, Peihong, et al. “Me 3 Si−SiMe 2 [ o CON( i Pr) 2 −C 6 H 4 ]: An Unsymmetrical Disilane Reagent for Regio‐ and Stereoselective Bis‐Silylation of Alkynes.” Angewandte Chemie - International Edition, vol. 57, no. 17, Mar. 2018, pp. 4769-4773. https://doi.org/10.1002/anie.201800513.