volume 57 issue 33 pages 10723-10727

Mechanochemical Rhodium(III)‐ and Gold(I)‐Catalyzed C−H Bond Alkynylations of Indoles under Solventless Conditions in Mixer Mills

Publication typeJournal Article
Publication date2018-06-28
scimago Q1
wos Q1
SJR5.550
CiteScore27.6
Impact factor16.9
ISSN14337851, 15213773
General Chemistry
Catalysis
Abstract

Mechanochemical activations in RhIII‐ and AuI‐catalyzed C−H alkynylations lead selectively to C2‐ and C3‐alkynylated indoles. The processes show excellent functional group tolerance, do not require additional heating and proceed under solventless conditions. Compared to solvent‐based standard protocols, the reaction times are shorter and the catalyst quantities lower resulting in high product yields under ambient atmosphere in mixer mills.

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GOST Copy
Hermann G. N. et al. Mechanochemical Rhodium(III)‐ and Gold(I)‐Catalyzed C−H Bond Alkynylations of Indoles under Solventless Conditions in Mixer Mills // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 33. pp. 10723-10727.
GOST all authors (up to 50) Copy
Hermann G. N., Unruh M. T., Jung S. H., Krings M., Bolm C. Mechanochemical Rhodium(III)‐ and Gold(I)‐Catalyzed C−H Bond Alkynylations of Indoles under Solventless Conditions in Mixer Mills // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 33. pp. 10723-10727.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/anie.201805778
UR - https://onlinelibrary.wiley.com/doi/10.1002/anie.201805778
TI - Mechanochemical Rhodium(III)‐ and Gold(I)‐Catalyzed C−H Bond Alkynylations of Indoles under Solventless Conditions in Mixer Mills
T2 - Angewandte Chemie - International Edition
AU - Hermann, Gary N
AU - Unruh, Marvin T
AU - Jung, Se Hyeong
AU - Krings, Maik
AU - Bolm, Carsten
PY - 2018
DA - 2018/06/28
PB - Wiley
SP - 10723-10727
IS - 33
VL - 57
PMID - 29889348
SN - 1433-7851
SN - 1521-3773
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Hermann,
author = {Gary N Hermann and Marvin T Unruh and Se Hyeong Jung and Maik Krings and Carsten Bolm},
title = {Mechanochemical Rhodium(III)‐ and Gold(I)‐Catalyzed C−H Bond Alkynylations of Indoles under Solventless Conditions in Mixer Mills},
journal = {Angewandte Chemie - International Edition},
year = {2018},
volume = {57},
publisher = {Wiley},
month = {jun},
url = {https://onlinelibrary.wiley.com/doi/10.1002/anie.201805778},
number = {33},
pages = {10723--10727},
doi = {10.1002/anie.201805778}
}
MLA
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MLA Copy
Hermann, Gary N., et al. “Mechanochemical Rhodium(III)‐ and Gold(I)‐Catalyzed C−H Bond Alkynylations of Indoles under Solventless Conditions in Mixer Mills.” Angewandte Chemie - International Edition, vol. 57, no. 33, Jun. 2018, pp. 10723-10727. https://onlinelibrary.wiley.com/doi/10.1002/anie.201805778.
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