Angewandte Chemie - International Edition

, volume 58 , issue 5 , pages 1479-1483

Azide Passivation of Black Phosphorus Nanosheets: Covalent Functionalization Affords Ambient Stability Enhancement

Yajuan Liu ¹

Pengfei Gao ²

Taiming Zhang ³

Xianjun Zhu ¹

Zhang Mengmeng ¹

Muqing Chen ¹

Pingwu Du ³

Guan-Wu Wang ⁴

Hongzhi Ji ³

Jinlong Yang ²

Shangfeng Yang ¹

Hide authors affiliations Show authors affiliations: 4 affiliations

Hefei National Laboratory for Physical Sciences at MicroscaleCAS Key Laboratory of Materials for Energy ConversionDepartment of Materials Science and EngineeringSynergetic Innovation Center of Quantum Information & Quantum PhysicsUniversity of Science and Technology of China Hefei 230026 China |

Hefei National Laboratory for Physical Sciences at MicroscaleDepartment of Chemical PhysicsSynergetic Innovation Center of Quantum Information & Quantum PhysicsUniversity of Science and Technology of China Hefei 230026 China |

Hefei National Laboratory for Physical Sciences at MicroscaleCAS Key Laboratory of Materials for Energy ConversionDepartment of Materials Science and Engineering, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials)University of Science and Technology of China Hefei 230026 China |

⁴

CAS Key Laboratory of Soft Matter ChemistryHefei National Laboratory for Physical Sciences at MicroscaleCollaborative Innovation Center of Chemistry for Energy Materials (iChEM)Department of ChemistryUniversity of Science and Technology of China Hefei 230026 China |

Publication type: Journal Article

Publication date: 2019-01-28

Wiley

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR: 5.550

CiteScore: 27.6

Impact factor: 16.9

ISSN: 14337851, 15213773

DOI: 10.1002/anie.201813218

Copy DOI

PubMed ID: 30536864

General Chemistry

Catalysis

Abstract

Two-dimensional (2D) black phosphorus (BP) has a unique band structure, but it suffers from low ambient stability owing to its high reactivity to oxygen. Covalent functionalization has been demonstrated to passivate the reactive BP effectively, however the reported covalent functionalization methods are quite limited to aryl diazonium and nucleophilic additions affording P-C and P-O-C single bonds, for which the retaining of one unpaired electron in the Group 15 phosphorus atom hampers the passivation effect. Now, covalent azide functionalization of BP nanosheets (BPNSs) is reported, leading to significant enhancement of the ambient stability of BP as confirmed by UV/Vis spectroscopic studies. The most stable configuration of the azide functionalized BPNSs (f-BPNSs) is predicted by theoretical calculations, featuring the grafting of benzoic acid moiety onto BPNSs via the unprecedented P=N double bonds formed through in situ nitrene as a reactive intermediate.

Found

1 citation

Faizullin Bulat

PhD in Chemistry

17 publications, 90 citations

h-index: 6

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Research interests

Colloidal nanoparticles

1 citation

Brylev Konstantin

🤝

DSc in Chemistry

135 publications, 3 382 citations

h-index: 33

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Research interests

Coordination Chemistry

Functional materials

Luminescence

Metal cluster complexes

Top-30

Journals

	1 2 3 4 5 6 7
Advanced Functional Materials	Advanced Functional Materials, 7, 4.46% Advanced Functional Materials 7 publications, 4.46%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 7, 4.46% Angewandte Chemie - International Edition 7 publications, 4.46%
Angewandte Chemie	Angewandte Chemie, 7, 4.46% Angewandte Chemie 7 publications, 4.46%
Chemical Engineering Journal	Chemical Engineering Journal, 6, 3.82% Chemical Engineering Journal 6 publications, 3.82%
ACS applied materials & interfaces	ACS applied materials & interfaces, 6, 3.82% ACS applied materials & interfaces 6 publications, 3.82%
Advanced Materials Interfaces	Advanced Materials Interfaces, 5, 3.18% Advanced Materials Interfaces 5 publications, 3.18%
Advanced Science	Advanced Science, 4, 2.55% Advanced Science 4 publications, 2.55%
Advanced Materials	Advanced Materials, 4, 2.55% Advanced Materials 4 publications, 2.55%
Nano Research	Nano Research, 3, 1.91% Nano Research 3 publications, 1.91%
Journal of Materials Science	Journal of Materials Science, 3, 1.91% Journal of Materials Science 3 publications, 1.91%
Chemistry - A European Journal	Chemistry - A European Journal, 3, 1.91% Chemistry - A European Journal 3 publications, 1.91%
ACS Applied Nano Materials	ACS Applied Nano Materials, 3, 1.91% ACS Applied Nano Materials 3 publications, 1.91%
Small	Small, 3, 1.91% Small 3 publications, 1.91%
Polymers	Polymers, 2, 1.27% Polymers 2 publications, 1.27%
Chinese Chemical Letters	Chinese Chemical Letters, 2, 1.27% Chinese Chemical Letters 2 publications, 1.27%
Sensors and Actuators, B: Chemical	Sensors and Actuators, B: Chemical, 2, 1.27% Sensors and Actuators, B: Chemical 2 publications, 1.27%
Journal of Power Sources	Journal of Power Sources, 2, 1.27% Journal of Power Sources 2 publications, 1.27%
Applied Surface Science	Applied Surface Science, 2, 1.27% Applied Surface Science 2 publications, 1.27%
Advanced Electronic Materials	Advanced Electronic Materials, 2, 1.27% Advanced Electronic Materials 2 publications, 1.27%
Advanced healthcare materials	Advanced healthcare materials, 2, 1.27% Advanced healthcare materials 2 publications, 1.27%
Batteries & Supercaps	Batteries & Supercaps, 2, 1.27% Batteries & Supercaps 2 publications, 1.27%
Accounts of Materials Research	Accounts of Materials Research, 2, 1.27% Accounts of Materials Research 2 publications, 1.27%
Chemical Reviews	Chemical Reviews, 2, 1.27% Chemical Reviews 2 publications, 1.27%
ACS Nano	ACS Nano, 2, 1.27% ACS Nano 2 publications, 1.27%
Chemical Society Reviews	Chemical Society Reviews, 2, 1.27% Chemical Society Reviews 2 publications, 1.27%
Chemical Science	Chemical Science, 2, 1.27% Chemical Science 2 publications, 1.27%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 2, 1.27% Journal of Materials Chemistry A 2 publications, 1.27%
Journal of Materials Chemistry B	Journal of Materials Chemistry B, 2, 1.27% Journal of Materials Chemistry B 2 publications, 1.27%
Nanoscale	Nanoscale, 2, 1.27% Nanoscale 2 publications, 1.27%
Analytical Imaging Techniques for Soft Matter Characterization	Analytical Imaging Techniques for Soft Matter Characterization, 2, 1.27% Analytical Imaging Techniques for Soft Matter Characterization 2 publications, 1.27%
	1 2 3 4 5 6 7

Publishers

	10 20 30 40 50 60
Wiley	Wiley, 56, 35.67% Wiley 56 publications, 35.67%
Elsevier	Elsevier, 36, 22.93% Elsevier 36 publications, 22.93%
American Chemical Society (ACS)	American Chemical Society (ACS), 20, 12.74% American Chemical Society (ACS) 20 publications, 12.74%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 18, 11.46% Royal Society of Chemistry (RSC) 18 publications, 11.46%
Springer Nature	Springer Nature, 14, 8.92% Springer Nature 14 publications, 8.92%
MDPI	MDPI, 4, 2.55% MDPI 4 publications, 2.55%
Frontiers Media S.A.	Frontiers Media S.A., 1, 0.64% Frontiers Media S.A. 1 publication, 0.64%
IOP Publishing	IOP Publishing, 1, 0.64% IOP Publishing 1 publication, 0.64%
Walter de Gruyter	Walter de Gruyter, 1, 0.64% Walter de Gruyter 1 publication, 0.64%
American Association for the Advancement of Science (AAAS)	American Association for the Advancement of Science (AAAS), 1, 0.64% American Association for the Advancement of Science (AAAS) 1 publication, 0.64%
Hindawi Limited	Hindawi Limited, 1, 0.64% Hindawi Limited 1 publication, 0.64%
Pleiades Publishing	Pleiades Publishing, 1, 0.64% Pleiades Publishing 1 publication, 0.64%
Oxford University Press	Oxford University Press, 1, 0.64% Oxford University Press 1 publication, 0.64%
Taylor & Francis	Taylor & Francis, 1, 0.64% Taylor & Francis 1 publication, 0.64%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 0.64% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 0.64%
	10 20 30 40 50 60

We do not take into account publications without a DOI.
Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

158

Cite this

GOST |

Cite this

GOST Copy

Liu Y. et al. Azide Passivation of Black Phosphorus Nanosheets: Covalent Functionalization Affords Ambient Stability Enhancement // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 5. pp. 1479-1483.

GOST all authors (up to 50) Copy

Liu Y., Gao P., Zhang T., Zhu X., Mengmeng Z., Chen M., Du P., Wang G., Ji H., Yang J., Yang S. Azide Passivation of Black Phosphorus Nanosheets: Covalent Functionalization Affords Ambient Stability Enhancement // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 5. pp. 1479-1483.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1002/anie.201813218

UR - https://doi.org/10.1002/anie.201813218

TI - Azide Passivation of Black Phosphorus Nanosheets: Covalent Functionalization Affords Ambient Stability Enhancement

T2 - Angewandte Chemie - International Edition

AU - Liu, Yajuan

AU - Gao, Pengfei

AU - Zhang, Taiming

AU - Zhu, Xianjun

AU - Mengmeng, Zhang

AU - Chen, Muqing

AU - Du, Pingwu

AU - Wang, Guan-Wu

AU - Ji, Hongzhi

AU - Yang, Jinlong

AU - Yang, Shangfeng

PY - 2019

DA - 2019/01/28

PB - Wiley

SP - 1479-1483

IS - 5

VL - 58

PMID - 30536864

SN - 1433-7851

SN - 1521-3773

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2019_Liu,

author = {Yajuan Liu and Pengfei Gao and Taiming Zhang and Xianjun Zhu and Zhang Mengmeng and Muqing Chen and Pingwu Du and Guan-Wu Wang and Hongzhi Ji and Jinlong Yang and Shangfeng Yang},

title = {Azide Passivation of Black Phosphorus Nanosheets: Covalent Functionalization Affords Ambient Stability Enhancement},

journal = {Angewandte Chemie - International Edition},

year = {2019},

volume = {58},

publisher = {Wiley},

month = {jan},

url = {https://doi.org/10.1002/anie.201813218},

number = {5},

pages = {1479--1483},

doi = {10.1002/anie.201813218}

}

MLA

Cite this

MLA Copy

Liu, Yajuan, et al. “Azide Passivation of Black Phosphorus Nanosheets: Covalent Functionalization Affords Ambient Stability Enhancement.” Angewandte Chemie - International Edition, vol. 58, no. 5, Jan. 2019, pp. 1479-1483. https://doi.org/10.1002/anie.201813218.

Publisher

Wiley

Journal

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR

5.550

CiteScore

27.6

Impact factor

16.9

ISSN

14337851 (Print)

15213773 (Electronic)