A Neutral Geminal Tin/Phosphorus Frustrated Lewis Pair
Philipp Holtkamp
1
,
Felix Friedrich
1
,
Erik Stratmann
1
,
A Mix
1
,
Beate Neumann
1
,
Hans-Georg Stammler
1
,
Publication type: Journal Article
Publication date: 2019-04-01
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
30758907
General Chemistry
Catalysis
Abstract
The geminal frustrated Lewis pair (FLP) (F5 C2 )3 SnCH2 P(tBu)2 (2) was prepared by reacting (F5 C2 )3 SnCl with LiCH2 P(tBu)2 . It is neutral and contains an extremely electronegatively substituted, but relatively soft (hard-soft acid-base, HSAB) acidic tin function. Its FLP-type reactivity was proven by reaction with a variety of small molecules (CO2 , SO2 , CS2 , PhNCO, HCl, (Ph3 P)AuCl). However, it shows no reaction in H/D scrambling experiments with H2 /D2 mixtures and binds CO2 reversibly, as was observed by VT-NMR spectroscopy. Compound 2 and all its adducts were completely characterized by means of multinuclear NMR spectroscopy, elemental analysis, and X-ray diffraction experiments.
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70
Total citations:
70
Citations from 2025:
5
(7.14%)
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MLA
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GOST
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Holtkamp P. et al. A Neutral Geminal Tin/Phosphorus Frustrated Lewis Pair // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 15. pp. 5114-5118.
GOST all authors (up to 50)
Copy
Holtkamp P., Friedrich F., Stratmann E., Mix A., Neumann B., Stammler H., Mitzel N. W. A Neutral Geminal Tin/Phosphorus Frustrated Lewis Pair // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 15. pp. 5114-5118.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201901037
UR - https://doi.org/10.1002/anie.201901037
TI - A Neutral Geminal Tin/Phosphorus Frustrated Lewis Pair
T2 - Angewandte Chemie - International Edition
AU - Holtkamp, Philipp
AU - Friedrich, Felix
AU - Stratmann, Erik
AU - Mix, A
AU - Neumann, Beate
AU - Stammler, Hans-Georg
AU - Mitzel, Norbert Werner
PY - 2019
DA - 2019/04/01
PB - Wiley
SP - 5114-5118
IS - 15
VL - 58
PMID - 30758907
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Holtkamp,
author = {Philipp Holtkamp and Felix Friedrich and Erik Stratmann and A Mix and Beate Neumann and Hans-Georg Stammler and Norbert Werner Mitzel},
title = {A Neutral Geminal Tin/Phosphorus Frustrated Lewis Pair},
journal = {Angewandte Chemie - International Edition},
year = {2019},
volume = {58},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/anie.201901037},
number = {15},
pages = {5114--5118},
doi = {10.1002/anie.201901037}
}
Cite this
MLA
Copy
Holtkamp, Philipp, et al. “A Neutral Geminal Tin/Phosphorus Frustrated Lewis Pair.” Angewandte Chemie - International Edition, vol. 58, no. 15, Apr. 2019, pp. 5114-5118. https://doi.org/10.1002/anie.201901037.