Angewandte Chemie - International Edition

, volume 60 , issue 22 , pages 12577-12584

Beyond Classical Coordination Chemistry: The First Case of a Triply Bridging Phosphine Ligand

Andrey Y Baranov ¹

Elena A. Pritchina ^{2, 3}

Alexei S Berezin ¹

Denis G. Samsonenko ¹

Vladimir P. Fedin ¹

Nataliya A. Belogorlova ⁴

N.P Gritsan ^{2, 3}

Alexander V. Artem'ev ¹

Hide authors affiliations Show authors affiliations: 4 affiliations

Nikolaev Institute of Inorganic Chemistry SB RAS 3 Acad. Lavrentiev Ave. 630090 Novosibirsk Russian Federation |

Voevodsky Institute of Chemical Kinetics and Combustion SB RAS 3 Institutskaya Str. 630090 Novosibirsk Russian Federation |

Novosibirsk State University 2 Pirogova Str. Novosibirsk 630090 Russian Federation |

⁴

A. E. Favorsky Irkutsk Institute of Chemistry SB RAS 1 Favorsky Str. 664033 Irkutsk Russian Federation |

Publication type: Journal Article

Publication date: 2021-04-22

Wiley

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR: 5.550

CiteScore: 27.6

Impact factor: 16.9

ISSN: 14337851, 15213773

DOI: 10.1002/anie.202103037

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PubMed ID: 33749065

General Chemistry

Catalysis

Abstract

Phosphines are notorious in acting exclusively as terminal donors, binding a single metal center. We have discovered that a non-traditional scenario is possible where the phosphorus(III) atom of a R3P ligand bridges three metal atoms at once. Such triply bridging pattern is first observed in the [Cu3(μ2-Hal)3L] (Hal=Cl, Br, or I) complexes, which also exhibit remarkable luminescence properties.

Found

3 citations

Karasik Andrey

DSc in Chemistry, professor, associate member of the Russian Academy of Sciences

224 publications, 2 625 citations

h-index: 26

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Research interests

Coordination Chemistry

Luminescence

Phosphorus ligands

2 citations

Filippov Oleg

🥼

DSc in Chemistry

137 publications, 2 416 citations, 45 reviews

h-index: 26

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

2 citations

Shubina Elena

DSc in Chemistry, professor

264 publications, 5 894 citations, 16 reviews

h-index: 38

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Research interests

Molecular spectroscopy

2 citations

Kiskin Mikhail

🥼 🤝

DSc in Chemistry, professor

408 publications, 5 128 citations

h-index: 31

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Research interests

Magnets

Nanoparticles

2 citations

Gerasimova Tatiana

PhD in Physics and Mathematics

115 publications, 1 752 citations

h-index: 21

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

2 citations

Strelnik Igor

🥼 🤝

PhD in Chemistry

60 publications, 820 citations, 5 reviews

h-index: 17

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Research interests

"Smart" materials

Coordination Chemistry

Inorganic Chemistry

Luminescent materials

Organic Chemistry

Organoelement chemistry

Organophosphorus chemistry

1 citation

Taydakov Ilya

🥼 🤝

DSc in Chemistry

209 publications, 2 305 citations, 47 reviews

h-index: 24

P.N. Lebedev Physical Institute of the Russian Academy of Sciences

Research interests

1,3-Diketones

Coordination Chemistry

Coordination chemistry of f-elements

Heterocyclic compounds

Lanthanides

Luminescence

Luminescent spectroscopy of lanthanides coordination compounds

Molecular spectroscopy

Organic synthesis

Rare-earth elements

1 citation

Doronina Evgeniya

PhD in Chemistry

41 publications, 434 citations

h-index: 13

A.E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences

1 citation

Davydova Maria

PhD in Chemistry

42 publications, 813 citations

h-index: 16

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Research interests

Circularly polarized luminescence

Clusters

Coordination chemistry

Coordination polymers

1 citation

Metlina Darya

16 publications, 264 citations

h-index: 8

P.N. Lebedev Physical Institute of the Russian Academy of Sciences

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Baranov A. Y. et al. Beyond Classical Coordination Chemistry: The First Case of a Triply Bridging Phosphine Ligand // Angewandte Chemie - International Edition. 2021. Vol. 60. No. 22. pp. 12577-12584.

GOST all authors (up to 50) Copy

Baranov A. Y., Pritchina E. A., Berezin A. S., Samsonenko D. G., Fedin V. P., Belogorlova N. A., Gritsan N., Artem'ev A. V. Beyond Classical Coordination Chemistry: The First Case of a Triply Bridging Phosphine Ligand // Angewandte Chemie - International Edition. 2021. Vol. 60. No. 22. pp. 12577-12584.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1002/anie.202103037

UR - https://doi.org/10.1002/anie.202103037

TI - Beyond Classical Coordination Chemistry: The First Case of a Triply Bridging Phosphine Ligand

T2 - Angewandte Chemie - International Edition

AU - Baranov, Andrey Y

AU - Pritchina, Elena A.

AU - Berezin, Alexei S

AU - Samsonenko, Denis G.

AU - Fedin, Vladimir P.

AU - Belogorlova, Nataliya A.

AU - Gritsan, N.P

AU - Artem'ev, Alexander V.

PY - 2021

DA - 2021/04/22

PB - Wiley

SP - 12577-12584

IS - 22

VL - 60

PMID - 33749065

SN - 1433-7851

SN - 1521-3773

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2021_Baranov,

author = {Andrey Y Baranov and Elena A. Pritchina and Alexei S Berezin and Denis G. Samsonenko and Vladimir P. Fedin and Nataliya A. Belogorlova and N.P Gritsan and Alexander V. Artem'ev},

title = {Beyond Classical Coordination Chemistry: The First Case of a Triply Bridging Phosphine Ligand},

journal = {Angewandte Chemie - International Edition},

year = {2021},

volume = {60},

publisher = {Wiley},

month = {apr},

url = {https://doi.org/10.1002/anie.202103037},

number = {22},

pages = {12577--12584},

doi = {10.1002/anie.202103037}

}

MLA

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MLA Copy

Baranov, Andrey Y., et al. “Beyond Classical Coordination Chemistry: The First Case of a Triply Bridging Phosphine Ligand.” Angewandte Chemie - International Edition, vol. 60, no. 22, Apr. 2021, pp. 12577-12584. https://doi.org/10.1002/anie.202103037.

Publisher

Wiley

Journal

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR

5.550

CiteScore

27.6

Impact factor

16.9

ISSN

14337851 (Print)

15213773 (Electronic)

Profiles

Vladimir P Fedin