Mechanochemical Grignard Reactions with Gaseous CO 2 and Sodium Methyl Carbonate**
Publication type: Journal Article
Publication date: 2022-01-19
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
34942056
General Chemistry
Catalysis
Abstract
A one-pot, three-step protocol for the preparation of Grignard reagents from organobromides in a ball mill and their subsequent reactions with gaseous carbon dioxide (CO2 ) or sodium methyl carbonate providing aryl and alkyl carboxylic acids in up to 82 % yield is reported. Noteworthy are the short reaction times and the significantly reduced solvent amounts [2.0 equiv. for liquid assisted grinding (LAG) conditions]. Unexpectedly, aryl bromides with methoxy substituents lead to symmetric ketones as major products.
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Metrics
83
Total citations:
83
Citations from 2025:
26
(31.32%)
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BibTex
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GOST
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Pfennig V. S. et al. Mechanochemical Grignard Reactions with Gaseous CO 2 and Sodium Methyl Carbonate** // Angewandte Chemie - International Edition. 2022. Vol. 61. No. 9.
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Pfennig V. S., Villella R. C., Nikodemus J., Bolm C. Mechanochemical Grignard Reactions with Gaseous CO 2 and Sodium Methyl Carbonate** // Angewandte Chemie - International Edition. 2022. Vol. 61. No. 9.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.202116514
UR - https://doi.org/10.1002/anie.202116514
TI - Mechanochemical Grignard Reactions with Gaseous CO 2 and Sodium Methyl Carbonate**
T2 - Angewandte Chemie - International Edition
AU - Pfennig, Victoria S
AU - Villella, Romina C
AU - Nikodemus, Julia
AU - Bolm, Carsten
PY - 2022
DA - 2022/01/19
PB - Wiley
IS - 9
VL - 61
PMID - 34942056
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2022_Pfennig,
author = {Victoria S Pfennig and Romina C Villella and Julia Nikodemus and Carsten Bolm},
title = {Mechanochemical Grignard Reactions with Gaseous CO 2 and Sodium Methyl Carbonate**},
journal = {Angewandte Chemie - International Edition},
year = {2022},
volume = {61},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/anie.202116514},
number = {9},
doi = {10.1002/anie.202116514}
}