Angewandte Chemie - International Edition, volume 61, issue 47

PNP Ligands in Cobalt‐Mediated Activation and Functionalization of White Phosphorus

Kuchkaev Airat M ^{1, 2}

Kuchkaev Aidar M. ^{1, 2}

Khayarov Khasan R ³

Zueva Ekaterina M ^{1, 4}

Dobrynin Alexey ¹

R. Islamov Daut ⁵

Yakhvarov Dmitry ^{1, 2}

Hide authors affiliations Show authors affiliations: 5 affiliations

Arbuzov Institute of Organic and Physical Chemistry FRC Kazan Scientific Center of RAS Arbuzov Street 8 Kazan 420088 Russian Federation

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

Alexander Butlerov Institute of Chemistry Kazan Federal University Kremlyovskaya Street 18 Kazan 420008 Russian Federation |

Institute of Physics Kazan Federal University Kremlyovskaya Street 18 Kazan 420008 Russian Federation |

⁴

Department of Inorganic Chemistry Kazan National Research Technological University Karl Marx Street 68 Kazan 420015 Russian Federation |

⁵

Laboratory for Structural Studies of Biomacromolecules FRC Kazan Scientific Center of RAS Lobachevskogo Street 2/31 Kazan 420111 Russian Federation |

Publication type: Journal Article

Publication date: 2022-10-06

Wiley

Journal: Angewandte Chemie - International Edition

Quartile SCImago

Quartile WOS

Impact factor: 16.6

ISSN: 14337851, 15213773

DOI: 10.1002/anie.202210973

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General Chemistry

Catalysis

Abstract

Transition-metal mediated white phosphorus activation is of high interest as an ecological alternative to P 4 chlorination pathway to the practically useful phosphorus products. Herein, we report a facile approach for P 4 activation, transformation and subsequent functionalization using cobalt complexes bearing PNP ligands. The use of N,N -bis(diphenylphosphino)amine as a ligand allows one to transform P 4 tetrahedron into a zig-zag chain with the formation of complex [Co(Ph 2 PNHP(Ph 2 ) PPPP P(Ph 2 )NHPPh 2 )]BF 4 ( 4 ). The presence of organic substituent at nitrogen atom in PNP ligand enables one to obtain complexes with η 1 -coordinated P 4 molecule, which indicates the crucial role of N-H bond in transformation of white phosphorus tetrahedron. Additionally, complex 4 can readily be functionalized by means of the reaction with Ph 2 PCl leading to the formation of a new complex bearing unique P 9 -ligand. The obtained results provide opportunities for facile construction of new polyphosphorus ligands in the coordination sphere of transition metal complexes.

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Citations by journals

	1 2
Chemistry - A European Journal	Chemistry - A European Journal, 2, 40% Chemistry - A European Journal 2 publications, 40%
European Journal of Organic Chemistry	European Journal of Organic Chemistry, 1, 20% European Journal of Organic Chemistry 1 publication, 20%
Inorganic Chemistry	Inorganic Chemistry, 1, 20% Inorganic Chemistry 1 publication, 20%
Russian Journal of Organic Chemistry	Russian Journal of Organic Chemistry, 1, 20% Russian Journal of Organic Chemistry 1 publication, 20%
	1 2

Citations by publishers

	1 2 3
Wiley	Wiley, 3, 60% Wiley 3 publications, 60%
American Chemical Society (ACS)	American Chemical Society (ACS), 1, 20% American Chemical Society (ACS) 1 publication, 20%
Pleiades Publishing	Pleiades Publishing, 1, 20% Pleiades Publishing 1 publication, 20%
	1 2 3

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Kuchkaev A. M. et al. PNP Ligands in Cobalt‐Mediated Activation and Functionalization of White Phosphorus // Angewandte Chemie - International Edition. 2022. Vol. 61. No. 47.

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Kuchkaev A. M., Kuchkaev A. M., Khayarov K. R., Zueva E. M., Dobrynin A., R. Islamov D., Yakhvarov D. PNP Ligands in Cobalt‐Mediated Activation and Functionalization of White Phosphorus // Angewandte Chemie - International Edition. 2022. Vol. 61. No. 47.

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RIS Copy

TY - JOUR

DO - 10.1002/anie.202210973

UR - https://doi.org/10.1002%2Fanie.202210973

TI - PNP Ligands in Cobalt‐Mediated Activation and Functionalization of White Phosphorus

T2 - Angewandte Chemie - International Edition

AU - Kuchkaev, Airat M

AU - Kuchkaev, Aidar M.

AU - Khayarov, Khasan R

AU - Zueva, Ekaterina M

AU - Dobrynin, Alexey

AU - R. Islamov, Daut

AU - Yakhvarov, Dmitry

PY - 2022

DA - 2022/10/06 00:00:00

PB - Wiley

IS - 47

VL - 61

SN - 1433-7851

SN - 1521-3773

ER -

BibTex

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BibTex Copy

@article{2022_Kuchkaev,

author = {Airat M Kuchkaev and Aidar M. Kuchkaev and Khasan R Khayarov and Ekaterina M Zueva and Alexey Dobrynin and Daut R. Islamov and Dmitry Yakhvarov},

title = {PNP Ligands in Cobalt‐Mediated Activation and Functionalization of White Phosphorus},

journal = {Angewandte Chemie - International Edition},

year = {2022},

volume = {61},

publisher = {Wiley},

month = {oct},

url = {https://doi.org/10.1002%2Fanie.202210973},

number = {47},

doi = {10.1002/anie.202210973}

}

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Publisher

Wiley

Journal

Angewandte Chemie - International Edition

Quartile SCImago

Quartile WOS

Impact factor

16.6

ISSN

14337851 (Print)
15213773 (Electronic)

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Laboratory of Organometallic and Coordination Compounds

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