Angewandte Chemie - International Edition, volume 63, issue 5
Polyoxometalate Li3PW12O40 and Li3PMo12O40 Electrolytes for High‐energy All‐solid‐state Lithium Batteries
Publication type: Journal Article
Publication date: 2023-12-22
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
Solid‐state lithium (Li) batteries promise both high energy density and safety while existing solid‐state electrolytes (SSEs) fail to satisfy the rigorous requirements of battery operations. Herein, novel polyoxometalate SSEs, Li3PW12O40 and Li3PMo12O40, are synthesized, which exhibit excellent interfacial compatibility with electrodes and chemical stability, overcoming the limitations of conventional SSEs. A high ionic conductivity of 0.89 mS cm−1 and a low activation energy of 0.23 eV are obtained due to the optimized three‐dimensional Li+ migration network of Li3PW12O40. Li3PW12O40 exhibits a wide window of electrochemical stability that can both accommodate the Li anode and high‐voltage cathodes. As a result, all‐solid‐state Li metal batteries fabricated with Li/Li3PW12O40/LiNi0.5Co0.2Mn0.3O2 display a stable cycling up to 100 cycles with a cutoff voltage of 4.35 V and an areal capacity of more than 4 mAh cm−2, as well as a cost‐competitive SSEs price of $5.68 kg−1. Moreover, Li3PMo12O40 homologous to Li3PW12O40 was obtained via isomorphous substitution, which formed a low‐resistance interface with Li3PW12O40. Applications of Li3PW12O40 and Li3PMo12O40 in Li‐air batteries further demonstrate that long cycle life (650 cycles) can be achieved. This strategy provides a facile, low‐cost strategy to construct efficient and scalable solid polyoxometalate electrolytes for high‐energy solid‐state Li metal batteries.
Top-30
Citations by journals
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Advanced Energy Materials
2 publications, 28.57%
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Journal of Energy Chemistry
1 publication, 14.29%
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Angewandte Chemie - International Edition
1 publication, 14.29%
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Angewandte Chemie
1 publication, 14.29%
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Russian Chemical Reviews
1 publication, 14.29%
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eScience
1 publication, 14.29%
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Citations by publishers
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Wiley
4 publications, 57.14%
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Elsevier
2 publications, 28.57%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 14.29%
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Guan D. et al. Polyoxometalate Li3PW12O40 and Li3PMo12O40 Electrolytes for High‐energy All‐solid‐state Lithium Batteries // Angewandte Chemie - International Edition. 2023. Vol. 63. No. 5.
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Guan D., Wang X., Song L., Miao C., Li J., Yuan X., Ma X., Xu J. Polyoxometalate Li3PW12O40 and Li3PMo12O40 Electrolytes for High‐energy All‐solid‐state Lithium Batteries // Angewandte Chemie - International Edition. 2023. Vol. 63. No. 5.
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TY - JOUR
DO - 10.1002/anie.202317949
UR - https://doi.org/10.1002/anie.202317949
TI - Polyoxometalate Li3PW12O40 and Li3PMo12O40 Electrolytes for High‐energy All‐solid‐state Lithium Batteries
T2 - Angewandte Chemie - International Edition
AU - Guan, De-Hui
AU - Wang, Xiao-xue
AU - Song, Li-Na
AU - Miao, Cheng‐Lin
AU - Li, Jian‐You
AU - Yuan, Xin-Yuan
AU - Ma, Xin‐Yue
AU - Xu, Jijing
PY - 2023
DA - 2023/12/22 00:00:00
PB - Wiley
IS - 5
VL - 63
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2023_Guan,
author = {De-Hui Guan and Xiao-xue Wang and Li-Na Song and Cheng‐Lin Miao and Jian‐You Li and Xin-Yuan Yuan and Xin‐Yue Ma and Jijing Xu},
title = {Polyoxometalate Li3PW12O40 and Li3PMo12O40 Electrolytes for High‐energy All‐solid‐state Lithium Batteries},
journal = {Angewandte Chemie - International Edition},
year = {2023},
volume = {63},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/anie.202317949},
number = {5},
doi = {10.1002/anie.202317949}
}