Synthesis of a new salphen-type titanium complex and its application in ethylene polymerization and copolymerization
Publication type: Journal Article
Publication date: 2010-04-01
scimago Q2
SJR: 0.515
CiteScore: 6.5
Impact factor: —
ISSN: 02682605, 10990739
DOI:
10.1002/aoc.1649
General Chemistry
Inorganic Chemistry
Abstract
TiCl2[salphen(di-tBu)] was synthesized, characterized and employed as pre-catalyst in ethylene homo- and copolymerization with propylene, 1-octene and 10-undecen-1-ol. X-ray diffraction study on the titanium complex revealed a distorted octahedral coordination of the central metal with a trans-Cl, cis-O, cis-N arrangement. The complex combined with MAO afforded moderate catalytic activities in ethylene polymerization. Furthermore the catalyst not only copolymerized ethylene with apolar monomer (propylene and 1-octene), but also possessed significant capability of incorporation with polar monomer (10-undecen-1-ol). Only single insertion of 1-octene unit in ethylene-co-1-octene polymer was detected by 13C NMR spectrum. Copyright © 2010 John Wiley & Sons, Ltd.
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8
Total citations:
8
Citations from 2024:
2
(25%)
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Wen X., Dong J. Synthesis of a new salphen-type titanium complex and its application in ethylene polymerization and copolymerization // Applied Organometallic Chemistry. 2010. Vol. 24. No. 7. pp. 503-508.
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Wen X., Dong J. Synthesis of a new salphen-type titanium complex and its application in ethylene polymerization and copolymerization // Applied Organometallic Chemistry. 2010. Vol. 24. No. 7. pp. 503-508.
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TY - JOUR
DO - 10.1002/aoc.1649
UR - https://doi.org/10.1002/aoc.1649
TI - Synthesis of a new salphen-type titanium complex and its application in ethylene polymerization and copolymerization
T2 - Applied Organometallic Chemistry
AU - Wen, Xiaojing
AU - Dong, Jin‐Yong
PY - 2010
DA - 2010/04/01
PB - Wiley
SP - 503-508
IS - 7
VL - 24
SN - 0268-2605
SN - 1099-0739
ER -
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BibTex (up to 50 authors)
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@article{2010_Wen,
author = {Xiaojing Wen and Jin‐Yong Dong},
title = {Synthesis of a new salphen-type titanium complex and its application in ethylene polymerization and copolymerization},
journal = {Applied Organometallic Chemistry},
year = {2010},
volume = {24},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/aoc.1649},
number = {7},
pages = {503--508},
doi = {10.1002/aoc.1649}
}
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MLA
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Wen, Xiaojing, and Jin‐Yong Dong. “Synthesis of a new salphen-type titanium complex and its application in ethylene polymerization and copolymerization.” Applied Organometallic Chemistry, vol. 24, no. 7, Apr. 2010, pp. 503-508. https://doi.org/10.1002/aoc.1649.