Vinyl polymerization of norbornene with dinuclear diimine nickel dichloride/MAO
Publication type: Journal Article
Publication date: 2003-04-17
scimago Q2
wos Q3
SJR: 0.572
CiteScore: 5.8
Impact factor: 2.8
ISSN: 00218995, 10974628
Materials Chemistry
Surfaces, Coatings and Films
General Chemistry
Polymers and Plastics
Abstract
Vinyl-addition polymerization of norbornene was accomplished by two novel dinuclear diimine nickel dichloride complexes in combination with methylaluminoxane (MAO). The activities were moderate. The catalyst structure, Al/Ni molar ratio, solvents, and polymerization temperature all affected the catalytic activities. The obtained polynorbornenes were characterized by 1H-NMR, 13C-NMR, FTIR, DSC, WAXD, and intrinsic viscosity measurements. The vinyl-addition polymers were amorphous but with a short-range order and high packing density. The polynorbornenes showed glass transition temperatures (Tg) above 240°C and decomposed above 400°C. The catalyst structure and polymerization conditions have effects on the molecular weight and the microstructure of the polymers. The nickel complex with bulkier substituents in the ligand produced polynorbornene with a higher packing density and higher regularity and, therefore, with higher Tg. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 3273–3278, 2003
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GOST
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Mi X. et al. Vinyl polymerization of norbornene with dinuclear diimine nickel dichloride/MAO // Journal of Applied Polymer Science. 2003. Vol. 88. No. 14. pp. 3273-3278.
GOST all authors (up to 50)
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Mi X., Ma Z., Cui N., Wang L., Ke Y., Hu Y. Vinyl polymerization of norbornene with dinuclear diimine nickel dichloride/MAO // Journal of Applied Polymer Science. 2003. Vol. 88. No. 14. pp. 3273-3278.
Cite this
RIS
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TY - JOUR
DO - 10.1002/app.12149
UR - https://doi.org/10.1002/app.12149
TI - Vinyl polymerization of norbornene with dinuclear diimine nickel dichloride/MAO
T2 - Journal of Applied Polymer Science
AU - Mi, Xia
AU - Ma, Zhi
AU - Cui, Nannan
AU - Wang, Leyong
AU - Ke, Yucai
AU - Hu, Youliang
PY - 2003
DA - 2003/04/17
PB - Wiley
SP - 3273-3278
IS - 14
VL - 88
SN - 0021-8995
SN - 1097-4628
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2003_Mi,
author = {Xia Mi and Zhi Ma and Nannan Cui and Leyong Wang and Yucai Ke and Youliang Hu},
title = {Vinyl polymerization of norbornene with dinuclear diimine nickel dichloride/MAO},
journal = {Journal of Applied Polymer Science},
year = {2003},
volume = {88},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/app.12149},
number = {14},
pages = {3273--3278},
doi = {10.1002/app.12149}
}
Cite this
MLA
Copy
Mi, Xia, et al. “Vinyl polymerization of norbornene with dinuclear diimine nickel dichloride/MAO.” Journal of Applied Polymer Science, vol. 88, no. 14, Apr. 2003, pp. 3273-3278. https://doi.org/10.1002/app.12149.