Wiley
Journal of Applied Polymer Science
,  volume 109 ,  issue 3 ,  pages 1529-1534

Highly active ethylene/hydroxyl comonomers copolymerization using metallocene catalysts

M T Expósito 1
, 
J. F. Vega 1
, 
Javier Ramos 1
, 
J Osío Barcina 2, 3, 4, 5
, 
Á García Martínez 2, 3, 4, 5
, 
C. Martín 6
, 
J. Martı́nez-Salazar 1
1
 
2
 
Departamento de Química Orgánica I
3
 
Facultad de Ciencias Químicas
4
 
5
 
Ciudad Universitaria s/n 28040 Madrid Spain | 
6
 
Centro Tecnológico Repsol‐YPF, Carretera A‐5, km 18, Móstoles, Madrid, Spain | 
Publication type: Journal Article
Publication date: 2008-04-18
Wiley
scimago Q2
wos Q3
SJR: 0.572
CiteScore: 5.8
Impact factor: 2.8
ISSN: 00218995, 10974628
Materials Chemistry
Surfaces, Coatings and Films
General Chemistry
Polymers and Plastics
Abstract
Ethylene was copolymerized with 10-undecen-1-ol and 5-hexen-1-ol using stereorigid [rac-ethylene(Ind)2ZrCl2], [rac-ethylene(H4Ind)2ZrCl2], and the new catalyst systems [rac-norbornane(Ind)2TiCl2] and [mesonorbornane(Ind)2TiCl2], activated with methylaluminoxane. The characterization of the copolymers by 13C NMR spectroscopy revealed that the polymerization products were copolymers and that the conversion of the polar comonomer was strongly favored in the case of the zirconocene precursors. Very high catalytic activity values, nearly independent on the amount of comonomer in the feed, and comonomer incorporations up to 25.4%-weight have been found for 10-undencen-1-ol comonomer. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008
Found 
Found 

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GOST Copy
Expósito M. T. et al. Highly active ethylene/hydroxyl comonomers copolymerization using metallocene catalysts // Journal of Applied Polymer Science. 2008. Vol. 109. No. 3. pp. 1529-1534.
GOST all authors (up to 50) Copy
Expósito M. T., Vega J. F., Ramos J., Osío Barcina J., García Martínez Á., Martín C., Martı́nez-Salazar J. Highly active ethylene/hydroxyl comonomers copolymerization using metallocene catalysts // Journal of Applied Polymer Science. 2008. Vol. 109. No. 3. pp. 1529-1534.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/app.28301
UR - https://doi.org/10.1002/app.28301
TI - Highly active ethylene/hydroxyl comonomers copolymerization using metallocene catalysts
T2 - Journal of Applied Polymer Science
AU - Expósito, M T
AU - Vega, J. F.
AU - Ramos, Javier
AU - Osío Barcina, J
AU - García Martínez, Á
AU - Martín, C.
AU - Martı́nez-Salazar, J.
PY - 2008
DA - 2008/04/18
PB - Wiley
SP - 1529-1534
IS - 3
VL - 109
SN - 0021-8995
SN - 1097-4628
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2008_Expósito,
author = {M T Expósito and J. F. Vega and Javier Ramos and J Osío Barcina and Á García Martínez and C. Martín and J. Martı́nez-Salazar},
title = {Highly active ethylene/hydroxyl comonomers copolymerization using metallocene catalysts},
journal = {Journal of Applied Polymer Science},
year = {2008},
volume = {109},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/app.28301},
number = {3},
pages = {1529--1534},
doi = {10.1002/app.28301}
}
MLA
Cite this
MLA Copy
Expósito, M. T., et al. “Highly active ethylene/hydroxyl comonomers copolymerization using metallocene catalysts.” Journal of Applied Polymer Science, vol. 109, no. 3, Apr. 2008, pp. 1529-1534. https://doi.org/10.1002/app.28301.