Journal of Applied Polymer Science, volume 109, issue 6, pages 4121-4129
Synthesis and properties of aliphatic polycarbonates derived from carbon dioxide, propylene oxide and maleic anhydride
Publication type: Journal Article
Publication date: 2008-09-15
Journal:
Journal of Applied Polymer Science
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 3
ISSN: 00218995, 10974628
Materials Chemistry
Surfaces, Coatings and Films
General Chemistry
Polymers and Plastics
Abstract
Terpolymerization of carbon dioxide (CO2) with propylene oxide (PO) and maleic anhydride (MA) was successfully carried out using supported zinc glutarate catalyst. Consequently giving high molecular weight poly(propylene carbonate maleate) (PPCMA) in a very high yield (72.5 g polymer/g catalyst). The resulting terpolymers were fully characterized by FTIR, 1H NMR, 13C NMR, and wide-angle X-ray diffraction (WAXD) techniques. NMR measurements showed that PPCMA had an almost alternating structure for the components of carbon dioxide and PO. The influence of molecular weight and MA content on the properties of PPCMA was also investigated. Differential scanning calorimetry (DSC) measurements revealed that the glass transition temperature (Tg) of PPCMA increased with increasing molecular weight. Thermogravimetric analysis (TGA) indicated that PPCMA51 exhibited a very high decomposition temperature (263°C) due to the introduction of the double bond of MA into the backbone of terpolymer. The terpolymers with double bonds can be readily subjected to crosslinking reaction in high temperature to give a slightly crosslinked PPCMA, which exhibit superior thermal stability. Tensile tests also showed that the mechanical properties of PPCMA increased with increasing molecular weight. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008
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Citations by publishers
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8 publications, 15.69%
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8 publications, 15.69%
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Springer Nature
7 publications, 13.73%
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5 publications, 9.8%
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Beilstein-Institut
1 publication, 1.96%
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China Science Publishing & Media
1 publication, 1.96%
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American Institute of Physics (AIP)
1 publication, 1.96%
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Taylor & Francis
1 publication, 1.96%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.96%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Song P. F. et al. Synthesis and properties of aliphatic polycarbonates derived from carbon dioxide, propylene oxide and maleic anhydride // Journal of Applied Polymer Science. 2008. Vol. 109. No. 6. pp. 4121-4129.
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Song P. F., Xiao M., Du F. G., Wang S., Gan L. Q., Liu G., Meng Y. L. Synthesis and properties of aliphatic polycarbonates derived from carbon dioxide, propylene oxide and maleic anhydride // Journal of Applied Polymer Science. 2008. Vol. 109. No. 6. pp. 4121-4129.
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TY - JOUR
DO - 10.1002/app.28449
UR - https://doi.org/10.1002/app.28449
TI - Synthesis and properties of aliphatic polycarbonates derived from carbon dioxide, propylene oxide and maleic anhydride
T2 - Journal of Applied Polymer Science
AU - Song, P F
AU - Xiao, M.
AU - Du, F G
AU - Wang, Shuanjin
AU - Gan, L Q
AU - Liu, G.Q.
AU - Meng, Y. L.
PY - 2008
DA - 2008/09/15 00:00:00
PB - Wiley
SP - 4121-4129
IS - 6
VL - 109
SN - 0021-8995
SN - 1097-4628
ER -
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@article{2008_Song,
author = {P F Song and M. Xiao and F G Du and Shuanjin Wang and L Q Gan and G.Q. Liu and Y. L. Meng},
title = {Synthesis and properties of aliphatic polycarbonates derived from carbon dioxide, propylene oxide and maleic anhydride},
journal = {Journal of Applied Polymer Science},
year = {2008},
volume = {109},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/app.28449},
number = {6},
pages = {4121--4129},
doi = {10.1002/app.28449}
}
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MLA
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Song, P. F., et al. “Synthesis and properties of aliphatic polycarbonates derived from carbon dioxide, propylene oxide and maleic anhydride.” Journal of Applied Polymer Science, vol. 109, no. 6, Sep. 2008, pp. 4121-4129. https://doi.org/10.1002/app.28449.