Journal of Applied Polymer Science
Fabrication and properties of crosslinked poly(propylene carbonate maleate) gel polymer electrolyte for lithium-ion battery
Publication type: Journal Article
Publication date: 2010-06-10
Journal:
Journal of Applied Polymer Science
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 3
ISSN: 00218995, 10974628
Materials Chemistry
Surfaces, Coatings and Films
General Chemistry
Polymers and Plastics
Abstract
The poly(propylene carbonate maleate) (PPCMA) was synthesized by the terpolymerization of carbon dioxide, propylene oxide, and maleic anhydride. The PPCMA polymer can be readily crosslinked using dicumyl peroxide (DCP) as crosslinking agent and then actived by absorbing liquid electrolyte to fabricate a novel PPCMA gel polymer electrolyte for lithium-ion battery. The thermal performance, electrolyte uptake, swelling ratio, ionic conductivity, and lithium ion transference number of the crosslinked PPCMA were then investigated. The results show that the Tg and the thermal stability increase, but the absorbing and swelling rates decrease with increasing DCP amount. The ionic conductivity of the PPCMA gel polymer electrolyte firstly increases and then decreases with increasing DCP ratio. The ionic conductivity of the PPCMA gel polymer electrolyte with 1.2 wt % of DCP reaches the maximum value of 8.43 × 10−3 S cm−1 at room temperature and 1.42 × 10−2 S cm−1 at 50°C. The lithium ion transference number of PPCMA gel polymer electrolyte is 0.42. The charge/discharge tests of the Li/PPCMA GPE/LiNi1/3Co1/3Mn1/3O2 cell were evaluated at a current rate of 0.1C and in voltage range of 2.8–4.2 V at room temperature. The results show that the initial discharge capacity of Li/PPCMA GPE/LiNi1/3Co1/3Mn1/3 O2 cell is 115.3 mAh g−1. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010
Top-30
Citations by journals
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1 publication, 11.11%
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1 publication, 11.11%
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RSC Advances
1 publication, 11.11%
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Russian Chemical Reviews
1 publication, 11.11%
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1 publication, 11.11%
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1 publication, 11.11%
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Ionics
1 publication, 11.11%
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1
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Citations by publishers
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1
2
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American Chemical Society (ACS)
2 publications, 22.22%
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Wiley
2 publications, 22.22%
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Elsevier
2 publications, 22.22%
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Royal Society of Chemistry (RSC)
1 publication, 11.11%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 11.11%
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Springer Nature
1 publication, 11.11%
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1
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Yu X. et al. Fabrication and properties of crosslinked poly(propylene carbonate maleate) gel polymer electrolyte for lithium-ion battery // Journal of Applied Polymer Science. 2010.
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Yu X., Xiao M., Wang S., Han D., Meng Y. L. Fabrication and properties of crosslinked poly(propylene carbonate maleate) gel polymer electrolyte for lithium-ion battery // Journal of Applied Polymer Science. 2010.
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TY - JOUR
DO - 10.1002/app.32480
UR - https://doi.org/10.1002/app.32480
TI - Fabrication and properties of crosslinked poly(propylene carbonate maleate) gel polymer electrolyte for lithium-ion battery
T2 - Journal of Applied Polymer Science
AU - Yu, Xiaoyuan
AU - Xiao, Min
AU - Wang, Shuangjin
AU - Han, Dongmei
AU - Meng, Y. L.
PY - 2010
DA - 2010/06/10 00:00:00
PB - Wiley
SN - 0021-8995
SN - 1097-4628
ER -
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@article{2010_Yu,
author = {Xiaoyuan Yu and Min Xiao and Shuangjin Wang and Dongmei Han and Y. L. Meng},
title = {Fabrication and properties of crosslinked poly(propylene carbonate maleate) gel polymer electrolyte for lithium-ion battery},
journal = {Journal of Applied Polymer Science},
year = {2010},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/app.32480},
doi = {10.1002/app.32480}
}