Journal of Applied Polymer Science

, volume 137 , issue 19 , pages 48656

Novel anion exchange membrane with low ionic resistance based on chloromethylated/quaternized‐grafted polystyrene for energy efficient electromembrane processes

Daniil Golubenko ^{1, 2}

Daniel V Golubenko ^{3, 4}

B. Van der Bruggen ^{5, 6}

Bart Van der Bruggen ^{7, 8}

A. B. Yaroslavtsev ^{1, 2, 3, 4}

Hide authors affiliations Show authors affiliations: 8 affiliations

Russian Academy of SciencesN.S. Kurnakov Institute of General and Inorganic Chemistry 31 Leninsky prospect, Moscow 119991 Russian Federation |

Russian Academy of SciencesInstitute of Problems of Chemical Physics Academician Semenov Avenue 1, Chernogolovka 142432 Moscow Region Russian Federation |

Russian Academy of Sciences N.S. Kurnakov Institute of General and Inorganic Chemistry 31 Leninsky prospect, Moscow 119991 Russian Federation |

⁴

Russian Academy of Sciences Institute of Problems of Chemical Physics Academician Semenov Avenue 1, Chernogolovka 142432 Moscow Region Russian Federation |

⁵

Department of Chemical EngineeringKU Leuven Celestijnenlaan 200F, B‐3001 Leuven Belgium |

⁶

Faculty of Engineering and the Built EnvironmentTshwane University of Technology Private Bag X680 Pretoria 0001 South Africa |

⁷

Department of Chemical Engineering KU Leuven Celestijnenlaan 200F, B‐3001 Leuven Belgium |

⁸

Faculty of Engineering and the Built Environment Tshwane University of Technology Private Bag X680 Pretoria 0001 South Africa |

Publication type: Journal Article

Publication date: 2019-11-01

Wiley

Journal of Applied Polymer Science

scimago Q2

wos Q3

SJR: 0.572

CiteScore: 5.8

Impact factor: 2.8

ISSN: 00218995, 10974628

DOI: 10.1002/app.48656

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Materials Chemistry

Surfaces, Coatings and Films

General Chemistry

Polymers and Plastics

Abstract

ABSTRACT

A novel anion‐exchange membrane has been manufactured by chloromethylation and subsequent quaternization of polystyrene within a graft copolymer films based on UV‐oxidized polymethylpentene. Particular attention is given to the kinetics of chloromethylation and the influence of the reaction conditions on the properties of the anion‐exchange membranes. By means of variation of the polystyrene content and its crosslinking degree we have obtained membranes that have an ion‐exchange capacity from 1.1 to 2.9 mmole g⁻¹, anion transport numbers between 91.0 and 95.5% and specific ionic conductivities ( ranging from 2 to 25 mS cm⁻¹. The developed membranes due to their low thickness and high conductivities have a remarkably low surface ionic resistance of around 0.6 Ω cm². It was calculated that the use of the developed materials will increase the efficiency of reverse electrodialysis energy production by 8–10% compared to the state of the art membranes. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 137, 48656.

Found

2 citations

Voropaeva Daria

PhD in Chemistry

33 publications, 506 citations, 18 reviews

h-index: 13

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Research interests

Green technologies

Lithium-ion batteries

Membrane materials

Sodium-ion batteries

1 citation

Manin Andrey

🥼 🤝

7 publications, 60 citations

h-index: 5

National Research University Higher School of Economics

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

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GOST |

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Golubenko D. et al. Novel anion exchange membrane with low ionic resistance based on chloromethylated/quaternized‐grafted polystyrene for energy efficient electromembrane processes // Journal of Applied Polymer Science. 2019. Vol. 137. No. 19. p. 48656.

GOST all authors (up to 50) Copy

Golubenko D., Golubenko D. V., Van der Bruggen B., Van der Bruggen B., Yaroslavtsev A. B. Novel anion exchange membrane with low ionic resistance based on chloromethylated/quaternized‐grafted polystyrene for energy efficient electromembrane processes // Journal of Applied Polymer Science. 2019. Vol. 137. No. 19. p. 48656.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1002/app.48656

UR - https://onlinelibrary.wiley.com/doi/10.1002/app.48656

TI - Novel anion exchange membrane with low ionic resistance based on chloromethylated/quaternized‐grafted polystyrene for energy efficient electromembrane processes

T2 - Journal of Applied Polymer Science

AU - Golubenko, Daniil

AU - Golubenko, Daniel V

AU - Van der Bruggen, B.

AU - Van der Bruggen, Bart

AU - Yaroslavtsev, A. B.

PY - 2019

DA - 2019/11/01

PB - Wiley

SP - 48656

IS - 19

VL - 137

SN - 0021-8995

SN - 1097-4628

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2019_Golubenko,

author = {Daniil Golubenko and Daniel V Golubenko and B. Van der Bruggen and Bart Van der Bruggen and A. B. Yaroslavtsev},

title = {Novel anion exchange membrane with low ionic resistance based on chloromethylated/quaternized‐grafted polystyrene for energy efficient electromembrane processes},

journal = {Journal of Applied Polymer Science},

year = {2019},

volume = {137},

publisher = {Wiley},

month = {nov},

url = {https://onlinelibrary.wiley.com/doi/10.1002/app.48656},

number = {19},

pages = {48656},

doi = {10.1002/app.48656}

}

MLA

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MLA Copy

Golubenko, Daniil, et al. “Novel anion exchange membrane with low ionic resistance based on chloromethylated/quaternized‐grafted polystyrene for energy efficient electromembrane processes.” Journal of Applied Polymer Science, vol. 137, no. 19, Nov. 2019, p. 48656. https://onlinelibrary.wiley.com/doi/10.1002/app.48656.

Publisher

Wiley

Journal

Journal of Applied Polymer Science

scimago Q2

wos Q3

SJR

0.572

CiteScore

5.8

Impact factor

2.8

ISSN

00218995 (Print)

10974628 (Electronic)

Labs

Laboratory of Ionics of Functional Materials

Profiles