Mixed-Ligand Zn-MOFs for Highly Luminescent Sensing of Nitro Compounds
Publication type: Journal Article
Publication date: 2013-02-20
scimago Q2
wos Q2
SJR: 0.751
CiteScore: 5.9
Impact factor: 3.3
ISSN: 18614728, 1861471X
PubMed ID:
23426992
General Chemistry
Organic Chemistry
Biochemistry
Abstract
Three Zn(II) metal-organic frameworks (Zn-MOFs), [Zn2(tib)(HL(1))(H2L(1))0.5]·2H2O (1), [Zn2(tib)(L(2))]·H2O (2) and [Zn3(tib)(L(3))2(H2O)6]·2 H2O (3), have been prepared by reactions of 1,3,5-tris(1-imidazolyl)benzene (tib), and biphenyl-3,3',4,4'-tetracarboxylic acid (H4L(1)), 4,4'-oxydiphthalic acid (H4L(2)), or benzene-1,3,5-tricarboxylic acid (H3L(3)) with corresponding Zn(II) salts, respectively. Single crystal structure analyses reveal that 1 and 2 are constructed by Zn-centered polyhedra, tib and multidentate tetracarboxylate ligands to form 3-dimensional frameworks. In contrast, when the tetracarboxylate ligands were replaced by tricarboxylate ligand, layered structure of 3 is produced. These compounds are further characterized by powder X-ray diffraction, element analyses, thermogravimetric analyses and photoluminescent spectroscopy. The luminescent properties of three Zn-MOFs dispersed in different solvents have been investigated systematically, demonstrating high sensitivity for the detection of nitro compounds via a fluorescence quenching mechanism.
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Total citations:
145
Citations from 2025:
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(4.14%)
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GOST
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Wang H., Yang W., SUN Z. Mixed-Ligand Zn-MOFs for Highly Luminescent Sensing of Nitro Compounds // Chemistry - An Asian Journal. 2013. Vol. 8. No. 5. pp. 982-989.
GOST all authors (up to 50)
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Wang H., Yang W., SUN Z. Mixed-Ligand Zn-MOFs for Highly Luminescent Sensing of Nitro Compounds // Chemistry - An Asian Journal. 2013. Vol. 8. No. 5. pp. 982-989.
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RIS
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TY - JOUR
DO - 10.1002/asia.201201184
UR - https://doi.org/10.1002/asia.201201184
TI - Mixed-Ligand Zn-MOFs for Highly Luminescent Sensing of Nitro Compounds
T2 - Chemistry - An Asian Journal
AU - Wang, Hao
AU - Yang, Wei-Ting
AU - SUN, ZHONGMING
PY - 2013
DA - 2013/02/20
PB - Wiley
SP - 982-989
IS - 5
VL - 8
PMID - 23426992
SN - 1861-4728
SN - 1861-471X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2013_Wang,
author = {Hao Wang and Wei-Ting Yang and ZHONGMING SUN},
title = {Mixed-Ligand Zn-MOFs for Highly Luminescent Sensing of Nitro Compounds},
journal = {Chemistry - An Asian Journal},
year = {2013},
volume = {8},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/asia.201201184},
number = {5},
pages = {982--989},
doi = {10.1002/asia.201201184}
}
Cite this
MLA
Copy
Wang, Hao, et al. “Mixed-Ligand Zn-MOFs for Highly Luminescent Sensing of Nitro Compounds.” Chemistry - An Asian Journal, vol. 8, no. 5, Feb. 2013, pp. 982-989. https://doi.org/10.1002/asia.201201184.