Hydrogen-Bonding Network Promoted [3+2] Cycloaddition: Asymmetric Catalytic Construction of Spiro-pseudoindoxyl Derivatives
Publication type: Journal Article
Publication date: 2016-02-16
scimago Q2
wos Q2
SJR: 0.751
CiteScore: 5.9
Impact factor: 3.3
ISSN: 18614728, 1861471X
PubMed ID:
26812234
General Chemistry
Organic Chemistry
Biochemistry
Abstract
The enantioselective construction of a spirocyclic quaternary stereogenic carbon center at the C2 position of indole has long been an elusive problem in organic synthesis. Herein, by employing a rationally designed hydrogen-bonding network activation strategy, for the first time, 2,2'-pyrrolidinyl-spirooxindole, which is a valuable and prevalent indole alkaloid scaffold, was directly obtained through a catalytic asymmetric [3+2] cycloaddition reaction with high yields and excellent stereoselectivities.
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Metrics
51
Total citations:
51
Citations from 2025:
1
(1.96%)
Cite this
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MLA
Cite this
GOST
Copy
Zhang L. et al. Hydrogen-Bonding Network Promoted [3+2] Cycloaddition: Asymmetric Catalytic Construction of Spiro-pseudoindoxyl Derivatives // Chemistry - An Asian Journal. 2016. Vol. 11. No. 6. pp. 834-838.
GOST all authors (up to 50)
Copy
Zhang L., Wang Y., Hu X., Xu P. Hydrogen-Bonding Network Promoted [3+2] Cycloaddition: Asymmetric Catalytic Construction of Spiro-pseudoindoxyl Derivatives // Chemistry - An Asian Journal. 2016. Vol. 11. No. 6. pp. 834-838.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/asia.201600013
UR - https://doi.org/10.1002/asia.201600013
TI - Hydrogen-Bonding Network Promoted [3+2] Cycloaddition: Asymmetric Catalytic Construction of Spiro-pseudoindoxyl Derivatives
T2 - Chemistry - An Asian Journal
AU - Zhang, Liang-Jie
AU - Wang, Yao
AU - Hu, Xiu-Qin
AU - Xu, Pengfei
PY - 2016
DA - 2016/02/16
PB - Wiley
SP - 834-838
IS - 6
VL - 11
PMID - 26812234
SN - 1861-4728
SN - 1861-471X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Zhang,
author = {Liang-Jie Zhang and Yao Wang and Xiu-Qin Hu and Pengfei Xu},
title = {Hydrogen-Bonding Network Promoted [3+2] Cycloaddition: Asymmetric Catalytic Construction of Spiro-pseudoindoxyl Derivatives},
journal = {Chemistry - An Asian Journal},
year = {2016},
volume = {11},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/asia.201600013},
number = {6},
pages = {834--838},
doi = {10.1002/asia.201600013}
}
Cite this
MLA
Copy
Zhang, Liang-Jie, et al. “Hydrogen-Bonding Network Promoted [3+2] Cycloaddition: Asymmetric Catalytic Construction of Spiro-pseudoindoxyl Derivatives.” Chemistry - An Asian Journal, vol. 11, no. 6, Feb. 2016, pp. 834-838. https://doi.org/10.1002/asia.201600013.