Synthesis, Isolation and Structures of Trifluoromethylated Fullerenes D 2 -C76 , C76 (1)(CF3 )10- 18
Publication type: Journal Article
Publication date: 2018-07-18
scimago Q2
wos Q2
SJR: 0.751
CiteScore: 5.9
Impact factor: 3.3
ISSN: 18614728, 1861471X
PubMed ID:
29874412
General Chemistry
Organic Chemistry
Biochemistry
Abstract
High-temperature trifluoromethylation of fullerene C76 chlorination products followed by HPLC separation of C76 (CF3 )n derivatives resulted in the isolation and X-ray structural characterization of thirteen C76 (1)(CF3 )n compounds including nine new isomers such as one isomer of C76 (1)(CF3 )10 , two C76 (1)(CF3 )12 , three C76 (1)(CF3 )14 , one C76 (1)(CF3 )16 , and two isomers of C76 (1)(CF3 )18 . Depending on their addition patterns, C76 (1)(CF3 )n isomers are divided into three subgroups and discussed in terms of trifluoromethylation pathways and relative formation energies.
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Tamm N. B. et al. Synthesis, Isolation and Structures of Trifluoromethylated Fullerenes D 2 -C76 , C76 (1)(CF3 )10- 18 // Chemistry - An Asian Journal. 2018. Vol. 13. No. 16. pp. 2027-2030.
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Tamm N. B., Ignateva D. V., Aslanov L. A., Troyanov S. Synthesis, Isolation and Structures of Trifluoromethylated Fullerenes D 2 -C76 , C76 (1)(CF3 )10- 18 // Chemistry - An Asian Journal. 2018. Vol. 13. No. 16. pp. 2027-2030.
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TY - JOUR
DO - 10.1002/asia.201800774
UR - https://doi.org/10.1002/asia.201800774
TI - Synthesis, Isolation and Structures of Trifluoromethylated Fullerenes D 2 -C76 , C76 (1)(CF3 )10- 18
T2 - Chemistry - An Asian Journal
AU - Tamm, Nadezhda B
AU - Ignateva, Daria V
AU - Aslanov, Leonid A.
AU - Troyanov, Sergey
PY - 2018
DA - 2018/07/18
PB - Wiley
SP - 2027-2030
IS - 16
VL - 13
PMID - 29874412
SN - 1861-4728
SN - 1861-471X
ER -
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BibTex (up to 50 authors)
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@article{2018_Tamm,
author = {Nadezhda B Tamm and Daria V Ignateva and Leonid A. Aslanov and Sergey Troyanov},
title = {Synthesis, Isolation and Structures of Trifluoromethylated Fullerenes D 2 -C76 , C76 (1)(CF3 )10- 18},
journal = {Chemistry - An Asian Journal},
year = {2018},
volume = {13},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/asia.201800774},
number = {16},
pages = {2027--2030},
doi = {10.1002/asia.201800774}
}
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MLA
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Tamm, Nadezhda B., et al. “Synthesis, Isolation and Structures of Trifluoromethylated Fullerenes D 2 -C76 , C76 (1)(CF3 )10- 18.” Chemistry - An Asian Journal, vol. 13, no. 16, Jul. 2018, pp. 2027-2030. https://doi.org/10.1002/asia.201800774.