anti ‐Markovnikov Iodofluorination of Alkenes
Publication type: Journal Article
Publication date: 2022-03-22
scimago Q2
wos Q2
SJR: 0.751
CiteScore: 5.9
Impact factor: 3.3
ISSN: 18614728, 1861471X
PubMed ID:
35266316
General Chemistry
Organic Chemistry
Biochemistry
Abstract
The fluorination of alkenes with electrophilic N-F type reagents usually occurs through a Markovnikov-type addition, and the anti-Markovnikov-type addition may require the use of a transition metal catalyst or an expensive catalyst. Herein we describe a convenient anti-Markovnikov iodofluorination of alkenes with Selectfluor/n Bu4 NI. A wide substrate scope and good functional group tolerance were observed. The process allows for the construction of various C-F bonds, especially tertiary C-F bonds. The remarkable features make this protocol attractive, including convenient operations, simple reaction conditions, and the installation of an iodine atom which provides possibilities for further transformations.
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Total citations:
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Citations from 2024:
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GOST
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Qian B. Yu. et al. anti ‐Markovnikov Iodofluorination of Alkenes // Chemistry - An Asian Journal. 2022. Vol. 17. No. 9.
GOST all authors (up to 50)
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Qian B. Yu., Zhang W., Lin J., Cao W., Xiao J. anti ‐Markovnikov Iodofluorination of Alkenes // Chemistry - An Asian Journal. 2022. Vol. 17. No. 9.
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TY - JOUR
DO - 10.1002/asia.202200184
UR - https://doi.org/10.1002/asia.202200184
TI - anti ‐Markovnikov Iodofluorination of Alkenes
T2 - Chemistry - An Asian Journal
AU - Qian, Bai Yu
AU - Zhang, Wei
AU - Lin, Jintong
AU - Cao, Weiguo
AU - Xiao, Ji-Chang
PY - 2022
DA - 2022/03/22
PB - Wiley
IS - 9
VL - 17
PMID - 35266316
SN - 1861-4728
SN - 1861-471X
ER -
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BibTex (up to 50 authors)
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@article{2022_Qian,
author = {Bai Yu Qian and Wei Zhang and Jintong Lin and Weiguo Cao and Ji-Chang Xiao},
title = {anti ‐Markovnikov Iodofluorination of Alkenes},
journal = {Chemistry - An Asian Journal},
year = {2022},
volume = {17},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/asia.202200184},
number = {9},
doi = {10.1002/asia.202200184}
}