Chemistry - An Asian Journal, volume 17, issue 9
anti ‐Markovnikov Iodofluorination of Alkenes
Publication type: Journal Article
Publication date: 2022-03-22
Journal:
Chemistry - An Asian Journal
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 4.1
ISSN: 18614728, 1861471X
General Chemistry
Organic Chemistry
Biochemistry
Abstract
The fluorination of alkenes with electrophilic N-F type reagents usually occurs through a Markovnikov-type addition, and the anti-Markovnikov-type addition may require the use of a transition metal catalyst or an expensive catalyst. Herein we describe a convenient anti-Markovnikov iodofluorination of alkenes with Selectfluor/n Bu4 NI. A wide substrate scope and good functional group tolerance were observed. The process allows for the construction of various C-F bonds, especially tertiary C-F bonds. The remarkable features make this protocol attractive, including convenient operations, simple reaction conditions, and the installation of an iodine atom which provides possibilities for further transformations.
Top-30
Citations by journals
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European Journal of Organic Chemistry
1 publication, 33.33%
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Russian Chemical Reviews
1 publication, 33.33%
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Advanced Synthesis and Catalysis
1 publication, 33.33%
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1
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Citations by publishers
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2
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Wiley
2 publications, 66.67%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 33.33%
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2
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Qian B. Yu. et al. anti ‐Markovnikov Iodofluorination of Alkenes // Chemistry - An Asian Journal. 2022. Vol. 17. No. 9.
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Qian B. Yu., Zhang W., Lin J., Cao W., Xiao J. anti ‐Markovnikov Iodofluorination of Alkenes // Chemistry - An Asian Journal. 2022. Vol. 17. No. 9.
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TY - JOUR
DO - 10.1002/asia.202200184
UR - https://doi.org/10.1002/asia.202200184
TI - anti ‐Markovnikov Iodofluorination of Alkenes
T2 - Chemistry - An Asian Journal
AU - Qian, Bai Yu
AU - Cao, Weiguo
AU - Xiao, Ji-Chang
AU - Lin, Jintong
AU - Zhang, Wei
PY - 2022
DA - 2022/03/22 00:00:00
PB - Wiley
IS - 9
VL - 17
SN - 1861-4728
SN - 1861-471X
ER -
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@article{2022_Qian,
author = {Bai Yu Qian and Weiguo Cao and Ji-Chang Xiao and Jintong Lin and Wei Zhang},
title = {anti ‐Markovnikov Iodofluorination of Alkenes},
journal = {Chemistry - An Asian Journal},
year = {2022},
volume = {17},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/asia.202200184},
number = {9},
doi = {10.1002/asia.202200184}
}