Wiley
Chemistry - An Asian Journal
,  volume 18 ,  issue 19

Organocatalytic Asymmetric Domino [3+2]‐Cycloaddition‐Acyl Transfer Reaction between Azomethine Ylides and α‐Nitro‐α,β‐Unsaturated Ketones

Publication type: Journal Article
Publication date: 2023-08-28
Wiley
scimago Q2
wos Q2
SJR: 0.751
CiteScore: 5.9
Impact factor: 3.3
ISSN: 18614728, 1861471X
General Chemistry
Organic Chemistry
Biochemistry
Abstract

Herein we have developed an organocatalytic asymmetric domino [3+2]‐cycloaddition‐acyl transfer reaction between in situ generated azomethine ylides and α‐nitro‐α,β‐unsaturated ketones. The desired penta‐substituted pyrrolidine products were obtained in high yields and in moderate to good enantio‐ and diastereoselectivities. Also, an isomerization reaction in silica gel was performed for the formation of another diastereomer in high yields with retention of enantioselectivities.

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Sahoo S. C., Parida C., Chandra Pan S. Organocatalytic Asymmetric Domino [3+2]‐Cycloaddition‐Acyl Transfer Reaction between Azomethine Ylides and α‐Nitro‐α,β‐Unsaturated Ketones // Chemistry - An Asian Journal. 2023. Vol. 18. No. 19.
GOST all authors (up to 50) Copy
Sahoo S. C., Parida C., Chandra Pan S. Organocatalytic Asymmetric Domino [3+2]‐Cycloaddition‐Acyl Transfer Reaction between Azomethine Ylides and α‐Nitro‐α,β‐Unsaturated Ketones // Chemistry - An Asian Journal. 2023. Vol. 18. No. 19.
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RIS Copy
TY - JOUR
DO - 10.1002/asia.202300563
UR - https://doi.org/10.1002/asia.202300563
TI - Organocatalytic Asymmetric Domino [3+2]‐Cycloaddition‐Acyl Transfer Reaction between Azomethine Ylides and α‐Nitro‐α,β‐Unsaturated Ketones
T2 - Chemistry - An Asian Journal
AU - Sahoo, Subas Chandra
AU - Parida, Chandrakanta
AU - Chandra Pan, Subhas
PY - 2023
DA - 2023/08/28
PB - Wiley
IS - 19
VL - 18
PMID - 37578733
SN - 1861-4728
SN - 1861-471X
ER -
BibTex
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BibTex (up to 50 authors) Copy
@article{2023_Sahoo,
author = {Subas Chandra Sahoo and Chandrakanta Parida and Subhas Chandra Pan},
title = {Organocatalytic Asymmetric Domino [3+2]‐Cycloaddition‐Acyl Transfer Reaction between Azomethine Ylides and α‐Nitro‐α,β‐Unsaturated Ketones},
journal = {Chemistry - An Asian Journal},
year = {2023},
volume = {18},
publisher = {Wiley},
month = {aug},
url = {https://doi.org/10.1002/asia.202300563},
number = {19},
doi = {10.1002/asia.202300563}
}