volume 19 issue 6

Assembly of Isoxazolyl Vinyl Silanes via Palladium‐Catalyzed Sequential Oxygenation/Vinylation of Ynone Oximes

Publication typeJournal Article
Publication date2024-02-01
scimago Q2
wos Q2
SJR0.751
CiteScore5.9
Impact factor3.3
ISSN18614728, 1861471X
General Chemistry
Organic Chemistry
Biochemistry
Abstract

A palladium‐catalyzed cascade cyclization/alkenylation for the assembly of synthetically valuable isoxazolyl vinylsilane derivative has been accomplished. Easily accessible ynone oximes, and available vinylsilane agents were used as the reaction starting materials This protocol features broad substrate scope, good functional group tolerance, and good step‐ and atom‐economy. Remarkably, this approach provides a new approach for the construction of structurally diverse isoxazolyl‐containing vinylsilanes with high molecular complexity, showing a promising application in synthetic and pharmaceutical chemistry.

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GOST Copy
Li J. et al. Assembly of Isoxazolyl Vinyl Silanes via Palladium‐Catalyzed Sequential Oxygenation/Vinylation of Ynone Oximes // Chemistry - An Asian Journal. 2024. Vol. 19. No. 6.
GOST all authors (up to 50) Copy
Li J., Hong C., Niu Y., Wang B., Jiang H. Assembly of Isoxazolyl Vinyl Silanes via Palladium‐Catalyzed Sequential Oxygenation/Vinylation of Ynone Oximes // Chemistry - An Asian Journal. 2024. Vol. 19. No. 6.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/asia.202301122
UR - https://doi.org/10.1002/asia.202301122
TI - Assembly of Isoxazolyl Vinyl Silanes via Palladium‐Catalyzed Sequential Oxygenation/Vinylation of Ynone Oximes
T2 - Chemistry - An Asian Journal
AU - Li, Jianxiao
AU - Hong, Chenjing
AU - Niu, Yanan
AU - Wang, Bowen
AU - Jiang, Huanfeng
PY - 2024
DA - 2024/02/01
PB - Wiley
IS - 6
VL - 19
PMID - 38224122
SN - 1861-4728
SN - 1861-471X
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2024_Li,
author = {Jianxiao Li and Chenjing Hong and Yanan Niu and Bowen Wang and Huanfeng Jiang},
title = {Assembly of Isoxazolyl Vinyl Silanes via Palladium‐Catalyzed Sequential Oxygenation/Vinylation of Ynone Oximes},
journal = {Chemistry - An Asian Journal},
year = {2024},
volume = {19},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/asia.202301122},
number = {6},
doi = {10.1002/asia.202301122}
}