Ruthenium Clusters on Carbon Nanofibers for Formic Acid Decomposition: Effect of Doping the Support with Nitrogen
Monika Zacharska
1
,
Olga Podyacheva
2
,
Lidiya Kibis
2
,
Andrey I Boronin
2
,
Boris V. Senkovskiy
3, 4
,
Oxana P. Taran
5
,
Artemiy B Ayusheev
5
,
V. N. Parmon
2
,
Witold Kwapinski
1
,
D BULUSHEV
2, 6
Publication type: Journal Article
Publication date: 2015-06-18
scimago Q1
wos Q2
SJR: 0.941
CiteScore: 6.1
Impact factor: 3.9
ISSN: 18673880, 18673899
Catalysis
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The catalytic properties of 1 wt % Ru catalysts with the same mean Ru cluster size of 1.4–1.5 nm supported on herringbone‐type carbon nanofibers with different N contents were compared for H2 production from formic acid decomposition. The Ru catalyst on the support with 6.8 wt % N gave a 1.5–2 times higher activity for the dehydrogenation reaction (CO2, H2) than the catalyst on the undoped support. The activity in the dehydration reaction (CO, H2O) was the same. As a result, the selectivity to H2 increased significantly from 83 to 92 % with N‐doping, and the activation energies for both reactions were close (55–58 kJ mol−1). The improvement could be explained by the presence of Ru clusters stabilized by pyridinic N located on the open edges of the external surface of the carbon nanofibers. This N may activate formic acid by the formation of an adduct (>NH+HCOO−) followed by its dehydrogenation on the adjacent Ru clusters.
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68
Total citations:
68
Citations from 2024:
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(10.29%)
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GOST
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Zacharska M. et al. Ruthenium Clusters on Carbon Nanofibers for Formic Acid Decomposition: Effect of Doping the Support with Nitrogen // ChemCatChem. 2015. Vol. 7. No. 18. pp. 2910-2917.
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Zacharska M., Podyacheva O., Kibis L., Boronin A. I., Senkovskiy B. V., Gerasimov E. Yu., Taran O. P., Ayusheev A. B., Parmon V. N., Kwapinski W., BULUSHEV D. Ruthenium Clusters on Carbon Nanofibers for Formic Acid Decomposition: Effect of Doping the Support with Nitrogen // ChemCatChem. 2015. Vol. 7. No. 18. pp. 2910-2917.
Cite this
RIS
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TY - JOUR
DO - 10.1002/cctc.201500216
UR - https://doi.org/10.1002/cctc.201500216
TI - Ruthenium Clusters on Carbon Nanofibers for Formic Acid Decomposition: Effect of Doping the Support with Nitrogen
T2 - ChemCatChem
AU - Zacharska, Monika
AU - Podyacheva, Olga
AU - Kibis, Lidiya
AU - Boronin, Andrey I
AU - Senkovskiy, Boris V.
AU - Gerasimov, Evgeny Yu
AU - Taran, Oxana P.
AU - Ayusheev, Artemiy B
AU - Parmon, V. N.
AU - Kwapinski, Witold
AU - BULUSHEV, D
PY - 2015
DA - 2015/06/18
PB - Wiley
SP - 2910-2917
IS - 18
VL - 7
SN - 1867-3880
SN - 1867-3899
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Zacharska,
author = {Monika Zacharska and Olga Podyacheva and Lidiya Kibis and Andrey I Boronin and Boris V. Senkovskiy and Evgeny Yu Gerasimov and Oxana P. Taran and Artemiy B Ayusheev and V. N. Parmon and Witold Kwapinski and D BULUSHEV},
title = {Ruthenium Clusters on Carbon Nanofibers for Formic Acid Decomposition: Effect of Doping the Support with Nitrogen},
journal = {ChemCatChem},
year = {2015},
volume = {7},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/cctc.201500216},
number = {18},
pages = {2910--2917},
doi = {10.1002/cctc.201500216}
}
Cite this
MLA
Copy
Zacharska, Monika, et al. “Ruthenium Clusters on Carbon Nanofibers for Formic Acid Decomposition: Effect of Doping the Support with Nitrogen.” ChemCatChem, vol. 7, no. 18, Jun. 2015, pp. 2910-2917. https://doi.org/10.1002/cctc.201500216.