Enhanced Activity and Recyclability of Palladium Complexes in the Catalytic Synthesis of Sodium Acrylate from Carbon Dioxide and Ethylene
Simone Manzini
1
,
Alban Cadu
1
,
Anna Corina Schmidt
1
,
Núria Huguet
2
,
Oliver Trapp
1, 3
,
Rocco Paciello
2
,
Thomas Schaub
1, 2
1
Catalysis Research Laboratory (CaRLa); Im Neuenheimer Feld 584 69120 Heidelberg Germany
|
2
Synthesis and Homogeneous Catalysis, BASF SE; Carl-Bosch-Str. 38 67056 Ludwigshafen Germany
|
Publication type: Journal Article
Publication date: 2016-12-28
scimago Q1
wos Q2
SJR: 0.941
CiteScore: 6.1
Impact factor: 3.9
ISSN: 18673880, 18673899
Catalysis
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The Pd-catalysed synthesis of sodium acrylate from ethylene and CO2 in the presence of alcoholate bases has been improved significantly. We used amide solvents such as N-cyclohexylpyrrolidone or N,N-dibutylformamide to achieve turnover numbers greater than 500 in one run, which is significantly higher than that of systems for this reaction reported previously. For the first time, we were able to recycle the catalyst without any additional regeneration step. With this system, it is possible to use the simple and easily recycled alcoholate base sodium isopropoxide to achieve good turnover numbers up to 200.
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Citations from 2024:
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GOST
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Manzini S. et al. Enhanced Activity and Recyclability of Palladium Complexes in the Catalytic Synthesis of Sodium Acrylate from Carbon Dioxide and Ethylene // ChemCatChem. 2016. Vol. 9. No. 12. pp. 2269-2274.
GOST all authors (up to 50)
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Manzini S., Cadu A., Schmidt A. C., Huguet N., Trapp O., Paciello R., Schaub T. Enhanced Activity and Recyclability of Palladium Complexes in the Catalytic Synthesis of Sodium Acrylate from Carbon Dioxide and Ethylene // ChemCatChem. 2016. Vol. 9. No. 12. pp. 2269-2274.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/cctc.201601150
UR - https://doi.org/10.1002/cctc.201601150
TI - Enhanced Activity and Recyclability of Palladium Complexes in the Catalytic Synthesis of Sodium Acrylate from Carbon Dioxide and Ethylene
T2 - ChemCatChem
AU - Manzini, Simone
AU - Cadu, Alban
AU - Schmidt, Anna Corina
AU - Huguet, Núria
AU - Trapp, Oliver
AU - Paciello, Rocco
AU - Schaub, Thomas
PY - 2016
DA - 2016/12/28
PB - Wiley
SP - 2269-2274
IS - 12
VL - 9
SN - 1867-3880
SN - 1867-3899
ER -
Cite this
BibTex (up to 50 authors)
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@article{2016_Manzini,
author = {Simone Manzini and Alban Cadu and Anna Corina Schmidt and Núria Huguet and Oliver Trapp and Rocco Paciello and Thomas Schaub},
title = {Enhanced Activity and Recyclability of Palladium Complexes in the Catalytic Synthesis of Sodium Acrylate from Carbon Dioxide and Ethylene},
journal = {ChemCatChem},
year = {2016},
volume = {9},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/cctc.201601150},
number = {12},
pages = {2269--2274},
doi = {10.1002/cctc.201601150}
}
Cite this
MLA
Copy
Manzini, Simone, et al. “Enhanced Activity and Recyclability of Palladium Complexes in the Catalytic Synthesis of Sodium Acrylate from Carbon Dioxide and Ethylene.” ChemCatChem, vol. 9, no. 12, Dec. 2016, pp. 2269-2274. https://doi.org/10.1002/cctc.201601150.