Synthesis of N‐Heterocycles by Reductive Cyclization of Nitro Compounds using Formate Esters as Carbon Monoxide Surrogates
Publication type: Journal Article
Publication date: 2017-11-27
scimago Q1
wos Q2
SJR: 0.941
CiteScore: 6.1
Impact factor: 3.9
ISSN: 18673880, 18673899
Catalysis
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A series of alkyl and aryl formate esters were evaluated as CO sources in the Pd‐ and Pd/Ru‐catalyzed reductive cyclization of substituted nitro compounds to afford heterocycles, especially indoles. Phenyl formate was found to be the most effective, and it allowed the desired products to be obtained in excellent yields, often higher than those previously reported with pressurized CO. Through detailed experiments and kinetic studies, we were able to discern between metal‐catalyzed and base‐mediated activation of phenyl formate and confirmed that just the base was effective in catalyzing its decarbonylation.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
5
6
|
|
|
European Journal of Organic Chemistry
6 publications, 11.11%
|
|
|
ChemCatChem
4 publications, 7.41%
|
|
|
Organic Letters
4 publications, 7.41%
|
|
|
Organic and Biomolecular Chemistry
4 publications, 7.41%
|
|
|
Chemical Communications
3 publications, 5.56%
|
|
|
Mendeleev Communications
2 publications, 3.7%
|
|
|
Catalysts
2 publications, 3.7%
|
|
|
Tetrahedron
2 publications, 3.7%
|
|
|
Asian Journal of Organic Chemistry
2 publications, 3.7%
|
|
|
ACS Omega
2 publications, 3.7%
|
|
|
Journal of Organic Chemistry
2 publications, 3.7%
|
|
|
Organic Chemistry Frontiers
2 publications, 3.7%
|
|
|
Chemistry of Heterocyclic Compounds
1 publication, 1.85%
|
|
|
Journal of Catalysis
1 publication, 1.85%
|
|
|
Journal of Organometallic Chemistry
1 publication, 1.85%
|
|
|
Tetrahedron Letters
1 publication, 1.85%
|
|
|
Advanced Synthesis and Catalysis
1 publication, 1.85%
|
|
|
ACS Combinatorial Science
1 publication, 1.85%
|
|
|
Chemical Science
1 publication, 1.85%
|
|
|
Chinese Journal of Chemistry
1 publication, 1.85%
|
|
|
Molecules
1 publication, 1.85%
|
|
|
SynOpen
1 publication, 1.85%
|
|
|
Beilstein Journal of Organic Chemistry
1 publication, 1.85%
|
|
|
Chemical Record
1 publication, 1.85%
|
|
|
Organometallics
1 publication, 1.85%
|
|
|
Chemistry - Methods
1 publication, 1.85%
|
|
|
Russian Chemical Reviews
1 publication, 1.85%
|
|
|
1
2
3
4
5
6
|
Publishers
|
2
4
6
8
10
12
14
16
18
20
|
|
|
Wiley
19 publications, 35.19%
|
|
|
American Chemical Society (ACS)
10 publications, 18.52%
|
|
|
Royal Society of Chemistry (RSC)
10 publications, 18.52%
|
|
|
Elsevier
5 publications, 9.26%
|
|
|
MDPI
4 publications, 7.41%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
2 publications, 3.7%
|
|
|
Springer Nature
1 publication, 1.85%
|
|
|
Georg Thieme Verlag KG
1 publication, 1.85%
|
|
|
Beilstein-Institut
1 publication, 1.85%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.85%
|
|
|
2
4
6
8
10
12
14
16
18
20
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
54
Total citations:
54
Citations from 2024:
11
(20.37%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Formenti D. et al. Synthesis of N‐Heterocycles by Reductive Cyclization of Nitro Compounds using Formate Esters as Carbon Monoxide Surrogates // ChemCatChem. 2017. Vol. 10. No. 1. pp. 148-152.
GOST all authors (up to 50)
Copy
Formenti D., Ferretti F., Ragaini F. Synthesis of N‐Heterocycles by Reductive Cyclization of Nitro Compounds using Formate Esters as Carbon Monoxide Surrogates // ChemCatChem. 2017. Vol. 10. No. 1. pp. 148-152.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/cctc.201701214
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.201701214
TI - Synthesis of N‐Heterocycles by Reductive Cyclization of Nitro Compounds using Formate Esters as Carbon Monoxide Surrogates
T2 - ChemCatChem
AU - Formenti, Dario
AU - Ferretti, Francesco
AU - Ragaini, Fabio
PY - 2017
DA - 2017/11/27
PB - Wiley
SP - 148-152
IS - 1
VL - 10
SN - 1867-3880
SN - 1867-3899
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Formenti,
author = {Dario Formenti and Francesco Ferretti and Fabio Ragaini},
title = {Synthesis of N‐Heterocycles by Reductive Cyclization of Nitro Compounds using Formate Esters as Carbon Monoxide Surrogates},
journal = {ChemCatChem},
year = {2017},
volume = {10},
publisher = {Wiley},
month = {nov},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.201701214},
number = {1},
pages = {148--152},
doi = {10.1002/cctc.201701214}
}
Cite this
MLA
Copy
Formenti, Dario, et al. “Synthesis of N‐Heterocycles by Reductive Cyclization of Nitro Compounds using Formate Esters as Carbon Monoxide Surrogates.” ChemCatChem, vol. 10, no. 1, Nov. 2017, pp. 148-152. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.201701214.