Chemical Engineering and Technology

, volume 39 , issue 5 , pages 865-873

Composition of the Green Oil in Hydrogenation of Acetylene over a Commercial Pd-Ag/Al₂O₃Catalyst

Jian Zhang ¹

Zhi Jun Sui ¹

Yian Zhu ¹

De Chen ²

Kake Zhu ¹

Weikang Yuan ¹

Hide authors affiliations Show authors affiliations: 2 affiliations

State Key Laboratory of Chemical Engineering, East China University of Science and Technology,Shanghai,China |

Department of Chemical Engineering, Norwegian University of Science and Technology, Trondheim,Norway |

Publication type: Journal Article

Publication date: 2016-04-05

Wiley

Chemical Engineering and Technology

scimago Q2

wos Q3

SJR: 0.374

CiteScore: 3.6

Impact factor: 1.6

ISSN: 09307516, 15214125

DOI: 10.1002/ceat.201600020

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General Chemistry

General Chemical Engineering

Industrial and Manufacturing Engineering

Abstract

Selective acetylene hydrogenation over a commercial Pd-Ag/Al2O3 catalyst was carried out under industrial operation conditions that correspond to the “tail-end” process. Pyrolysis gas chromatography-mass spectrometry was used to analyze the composition of the green oil. C8–C30 linear hydrocarbons with even carbon-numbered chains were detected as the main components of the green oil. Its chain length increased with operating time, temperature, and hydrogen partial pressure, and decreased with acetylene partial pressure. The composition of the green oil deviates from the Anderson-Schulz-Flory distribution. Both coupling-hydrogenation and hydrogenation-coupling mechanisms are involved in green oil formation.

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2 citations

Shlyapin Dmitry

83 publications, 954 citations, 7 reviews

h-index: 18

Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences

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GOST |

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GOST Copy

Zhang J. et al. Composition of the Green Oil in Hydrogenation of Acetylene over a Commercial Pd-Ag/Al2O3Catalyst // Chemical Engineering and Technology. 2016. Vol. 39. No. 5. pp. 865-873.

GOST all authors (up to 50) Copy

Zhang J., Sui Z. J., Zhu Y., Chen D., Zhu K., Yuan W. Composition of the Green Oil in Hydrogenation of Acetylene over a Commercial Pd-Ag/Al2O3Catalyst // Chemical Engineering and Technology. 2016. Vol. 39. No. 5. pp. 865-873.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/ceat.201600020

UR - https://doi.org/10.1002/ceat.201600020

TI - Composition of the Green Oil in Hydrogenation of Acetylene over a Commercial Pd-Ag/Al2O3Catalyst

T2 - Chemical Engineering and Technology

AU - Zhang, Jian

AU - Sui, Zhi Jun

AU - Zhu, Yian

AU - Chen, De

AU - Zhu, Kake

AU - Yuan, Weikang

PY - 2016

DA - 2016/04/05

PB - Wiley

SP - 865-873

IS - 5

VL - 39

SN - 0930-7516

SN - 1521-4125

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2016_Zhang,

author = {Jian Zhang and Zhi Jun Sui and Yian Zhu and De Chen and Kake Zhu and Weikang Yuan},

title = {Composition of the Green Oil in Hydrogenation of Acetylene over a Commercial Pd-Ag/Al2O3Catalyst},

journal = {Chemical Engineering and Technology},

year = {2016},

volume = {39},

publisher = {Wiley},

month = {apr},

url = {https://doi.org/10.1002/ceat.201600020},

number = {5},

pages = {865--873},

doi = {10.1002/ceat.201600020}

}

MLA

Cite this

MLA Copy

Zhang, Jian, et al. “Composition of the Green Oil in Hydrogenation of Acetylene over a Commercial Pd-Ag/Al2O3Catalyst.” Chemical Engineering and Technology, vol. 39, no. 5, Apr. 2016, pp. 865-873. https://doi.org/10.1002/ceat.201600020.

Publisher

Wiley

Journal

Chemical Engineering and Technology

scimago Q2

wos Q3

SJR

0.374

CiteScore

3.6

Impact factor

1.6

ISSN

09307516 (Print)

15214125 (Electronic)