Trimeric Perfluoro-ortho-phenylenemercury: A Versatile Lewis Acidic Host
Publication type: Journal Article
Publication date: 2003-11-07
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
14613128
General Chemistry
Catalysis
Organic Chemistry
Abstract
Trimeric perfluoro-ortho-phenylenemercury (1) constitutes one of the simplest trifunctional Lewis acidic hosts. In addition to cooperative effects arising from the proximity of the mercury(II) centers, the electron-withdrawing properties of the backbone and the accessibility of the electrophilic sites lead to the facile complexation of neutral and electron rich substrates. The planarity of the structure as well as its overall polarizability compounded with relativistic effects at mercury also permits the occurrence of non-covalent interactions and accounts for the tendency of this compound to form cofacial dimers. Collectively, the Lewis acidic properties of 1 as well as its ability to engage in non-covalent interactions can be held responsible for its ability to form extended binary supramolecular stacks with arenes. The photoluminescence observed in some of these supramolecular complexes corresponds to the phosphorescence of the aromatic substrate and indicate the occurrence of a mercury heavy atom effect.
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Total citations:
66
Citations from 2025:
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GOST
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Haneline M. R., Taylor R. E., Gabbaï F. P. Trimeric Perfluoro-ortho-phenylenemercury: A Versatile Lewis Acidic Host // Chemistry - A European Journal. 2003. Vol. 9. No. 21. pp. 5188-5193.
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Haneline M. R., Taylor R. E., Gabbaï F. P. Trimeric Perfluoro-ortho-phenylenemercury: A Versatile Lewis Acidic Host // Chemistry - A European Journal. 2003. Vol. 9. No. 21. pp. 5188-5193.
Cite this
RIS
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TY - JOUR
DO - 10.1002/chem.200305109
UR - https://doi.org/10.1002/chem.200305109
TI - Trimeric Perfluoro-ortho-phenylenemercury: A Versatile Lewis Acidic Host
T2 - Chemistry - A European Journal
AU - Haneline, Mason R.
AU - Taylor, Robert E.
AU - Gabbaï, François P.
PY - 2003
DA - 2003/11/07
PB - Wiley
SP - 5188-5193
IS - 21
VL - 9
PMID - 14613128
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
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@article{2003_Haneline,
author = {Mason R. Haneline and Robert E. Taylor and François P. Gabbaï},
title = {Trimeric Perfluoro-ortho-phenylenemercury: A Versatile Lewis Acidic Host},
journal = {Chemistry - A European Journal},
year = {2003},
volume = {9},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/chem.200305109},
number = {21},
pages = {5188--5193},
doi = {10.1002/chem.200305109}
}
Cite this
MLA
Copy
Haneline, Mason R., et al. “Trimeric Perfluoro-ortho-phenylenemercury: A Versatile Lewis Acidic Host.” Chemistry - A European Journal, vol. 9, no. 21, Nov. 2003, pp. 5188-5193. https://doi.org/10.1002/chem.200305109.